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About This Item
Linear Formula:
[(CH3)3C]2NO
CAS Number:
Molecular Weight:
145.24
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22
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grade
technical grade
assay
90%
refractive index
n20/D 1.435 (lit.)
bp
74-75 °C/34 mmHg (lit.)
functional group
amine
storage temp.
2-8°C
SMILES string
CC(C)(C)N([O])C(C)(C)C
InChI
1S/C8H18NO/c1-7(2,3)9(10)8(4,5)6/h1-6H3
InChI key
CKJMHSMEPSUICM-UHFFFAOYSA-N
Application
Di-tert-butyl nitroxide (DTBN) can be used as:
- An additive for the synthesis of N-sulfenylimines by oxidative coupling of amines and disulfides or thiols using a copper-based metal-organic framework (MOF) as a catalyst.[1]
- An initiator in the controlled radical polymerization reactions.[2][3]
- A reagent in the preparation of N-aroyl-o-aroyl-N-tert-butylhdroxylamines by reacting with aromatic acid chlorides.[4]
Reagent for the room-temperature oxidation of primary and secondary benzylamines to imines[5] and for the ESR study of Lewis acid centers in Zeolite X.[6]
Spin label. Has been used in localization of lipid microdomains and thermal phenomena in murine stratum corneum.
accessory
Product No.
Description
Pricing
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
114.8 °F - closed cup
flash_point_c
46 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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