738883

1-Methyl-2-azaadamantane-N-oxyl

97%

• Synonym(s): 1-Me-AZADO
• Empirical Formula (Hill Notation): C₁₀H₁₆NO
• CAS Number: 872598-44-2
• Molecular Weight: 166.24
• MDL number: MFCD34679793
• UNSPSC Code: 12352000
• PubChem Substance ID: 329765308
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 97%
• form: solid
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 87-93 °C
• greener alternative category: Aligned,
• storage temp.: 2-8°C
• SMILES string: CC12CC3CC(CC(C3)N1[O])C2
• InChI: 1S/C10H16NO/c1-10-5-7-2-8(6-10)4-9(3-7)11(10)12/h7-9H,2-6H2,1H3
• InChI key: IBNXYCCLPCGKDM-UHFFFAOYSA-N

Description

General description

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO), a sterically less hindered nitroxyl radical,[1] is widely used as catalyst.[2] It is chemically stable and exhibits superior catalytic performance.[2]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

application

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO) may be employed as catalyst for the aerobic oxidation of alcohols[2] and sterically hindered alcohols.[1]

Catalytic oxidant for greener oxidation of alcohols under aerobic, solvent-free conditions. Recoverable and recyclable.

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Other Notes

2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable