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138576

Sigma-Aldrich

1-Adamantylamine

97%

Synonym(s):

1-Aminoadamantane

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About This Item

Empirical Formula (Hill Notation):
C10H17N
CAS Number:
768-94-5
Molecular Weight:
151.25
Beilstein/REAXYS Number:
2204333
EC Number:
212-201-2
MDL number:
MFCD00074732
UNSPSC Code:
12352100
PubChem Substance ID:
24848359
NACRES:
NA.22

Quality Level

200

assay

97%

mp

206-208 °C (lit.)

solubility

1 M HCl: soluble 5%, clear to hazy, colorless to faint yellow or tan

SMILES string

NC12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C10H17N/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6,11H2/t7-,8+,9-,10-

InChI key

DKNWSYNQZKUICI-CHIWXEEVSA-N

Gene Information

human ... GRIN2A(2903)

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Application

1-Adamantylaminecan be used as a reactant to synthesize:
  • Adamantyl ureas by reacting with isocyanates in the presence of triethylamine.
  • N-(1-adamantyl)-2-chloroacetamide from chloroacetyl chloride in the presence of potassium carbonate.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sigma-Aldrich

8.18383

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Dinesh Addla et al.
Bioorganic & medicinal chemistry letters, 24(8), 1974-1979 (2014-04-01)
A series of novel 1,2,3-triazole-adamantylacetamide hybrids 5a-u, designed by combining bioactive fragments from antitubercular I-A09 and substituted adamantyl urea, were synthesized using copper catalyzed click chemistry. N-(1-Adamantyl)-2-azido acetamide 3 prepared from 1-adamantylamine was reacted with a series of alkyl/aryl acetylenes
Márió Gajdács et al.
Antibiotics (Basel, Switzerland), 8(4) (2019-12-22)
Background: The emergence of multidrug-resistant organisms (MDROs) is a global public health issue, severely hindering clinicians in administering appropriate antimicrobial therapy. Drug repurposing is a drug development strategy, during which new pharmacological applications are identified for already approved drugs. From
Zari Hooshyar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 173, 144-150 (2016-09-18)
In this study, we describe the synthesis of a new quantum dots (QDs) by embedding glutathione capped CdTe/ZnS QDs into cationic starch biopolymer (CS-GSH-CdTe/ZnS QDs). The fluorescence intensity of prepared QDs was significantly enhanced. When QDs interacted with rifampicin, the
Terminal Modification with 1-Adamantylamine to Endow Hyperbranched Polyamidoamine with Thermo-/pH-Responsive Properties.
Guo Z, et al.
Macromolecular Rapid Communications, 29(21), 1746-1751 (2008)
Jinglun Huang et al.
The Journal of organic chemistry, 72(1), 204-208 (2006-12-30)
The enantioselective Strecker reaction of N-diphenylphosphinoyl ketoimines has been achieved by use of in situ prepared chiral N,N'-dioxide catalyst from l-piperidinamide 3f and m-chloroperoxybenzoic acid (m-CPBA). Excellent yields (up to 99%) and high enantioselectivities (up to 92% ee) were obtained.
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