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109223

Sigma-Aldrich

1-Bromoadamantane

99%

Synonym(s):

1-Adamantyl bromide

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About This Item

Empirical Formula (Hill Notation):
C10H15Br
CAS Number:
768-90-1
Molecular Weight:
215.13
Beilstein/REAXYS Number:
1098857
EC Number:
212-200-7
MDL number:
MFCD00074721
UNSPSC Code:
12352100
PubChem Substance ID:
24846896
NACRES:
NA.22

assay

99%

mp

116-118 °C (lit.)

SMILES string

BrC12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C10H15Br/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-

InChI key

VQHPRVYDKRESCL-CHIWXEEVSA-N

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General description

1-Bromoadamantane forms inclusion complexes with α-, β-, and γ-cyclodextrins. It causes the alkylation of Co(II) complexes of β-diketones.

Application

1-Bromoadamantane was used in the synthesis of a new organic–organic nanoscale composite thin-film dielectric.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

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Alkylation of ?-diketones through their co (II), co (III) and zn (II) complexes. 1-Bromoadamantane as alkylating agent.
Gonzalez A, et al.
Tetrahedron Letters, 26(31), 3735-3738 (1985)
P. M. Ivanov et al.
The Journal of organic chemistry, 61(20), 7012-7017 (1996-10-04)
The inclusion complexes between the most commonly used cyclodextrins (alpha-, beta-, and gamma-CD) and 1-bromoadamantane were prepared and studied experimentally by NMR methods and by molecular dynamics simulations (AMBER force field) with solvation. The NMR results suggest host/guest ratios of
Jitendra N Tiwari et al.
ChemSusChem, 3(9), 1051-1056 (2010-07-14)
A new organic-organic nanoscale composite thin-film (NCTF) dielectric has been synthesized by solution deposition of 1-bromoadamantane and triblock copolymer (Pluronic P123, BASF, EO20-PO70-EO20), in which the precursor solution has been achieved with organic additives. We have used a sol-gel process
Cheng Li et al.
Analytica chimica acta, 1066, 121-130 (2019-04-28)
A visual, rapid, and sensitive method for the detection of two algal metabolites, geosmin (GSM) and 2-methylisoborneol (2-MIB) using a competitive displacement technique based on molecular imprinted polymers (MIPs) and fluorescent tags was developed. In this method, fluorescent tags that

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