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467901

Supelco

硫酸镍(II) 六水合物

≥99.99% trace metals basis

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About This Item

線性公式:
NiSO4 · 6H2O
CAS號碼:
分子量::
262.85
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

等級

for inorganic trace analysis

品質等級

蒸汽密度

2.07 (vs air)

化驗

≥99.99% trace metals basis

形狀

solid

雜質

≤0.002% N compounds
≤0.005% insolubles
<100 ppm total metallic impurities

負離子痕跡

chloride (Cl-): ≤0.001%

正離子痕跡

Ca: ≤0.005%
Co: ≤0.002%
Cu: ≤0.005%
Fe: ≤0.001%
K: ≤0.01%
Mg: ≤0.005%
Mn: ≤0.002%
Na: ≤0.05%

SMILES 字串

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI 密鑰

RRIWRJBSCGCBID-UHFFFAOYSA-L

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一般說明

六水合硫酸镍(NiSO4·6H2O),俗称镍矾,是一种天然存在的对映体矿物。它在单斜空间群 C2/C 中结晶。研究了其各种多晶型形式的晶体结构。据报道,手性六水合硫酸镍会引起不对称的自催化作用。采用热重分析仪 (TG) 和 X 射线粉末衍射仪 (XRD) 研究了六水合硫酸镍在空气和氦气气氛中的热降解行为。

應用


  • Improvement of ion chromatography with ultraviolet photometric detection and comparison with conductivity detection for the determination of serum cations.: This study explores advanced ion chromatography techniques for analyzing serum cations, where Nickel(II) sulfate hexahydrate may be used as a standard or in method development. The research compares ultraviolet photometric detection with conductivity detection, enhancing analytical methods for precise cation analysis in various samples, which can be crucial for environmental and clinical chemistry (Shintani H, 1985).

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

標靶器官

Respiratory Tract

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis.
Matsumoto A, et al.
New. J. Chem., 39(9), 6742-6745 (2015)
Structure of monoclinic nickel (II) sulfate hexahydrate.
Gerkin RE and Reppart WJ.
Acta Crystallographica Section C, Crystal Structure Communications, 44(8), 1486-1488 (1988)
Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Mechanism and kinetics of thermal decomposition of nickel (II) sulfate (VI) hexahydrate.
Tomaszewicz E and Kotfica M.
Journal of Thermal Analysis and Calorimetry, 77(1), 25-31 (2004)
Charlotte G Mortz et al.
Pediatric allergy and immunology : official publication of the European Society of Pediatric Allergy and Immunology, 24(1), 84-87 (2013-01-22)
We have previously reported patch test reactivity to nickel sulphate in a cohort of unselected infants tested repeatedly at 3-18 months of age. A reproducible positive reaction at 12 and 18 months was selected as a sign of nickel sensitivity provided a

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