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402990

Sigma-Aldrich

一氯化碘

ACS reagent, 1.10±0.1 I/Cl ratio basis

同義詞:

氯化碘

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About This Item

線性公式:
ICl
CAS號碼:
7790-99-0
分子量：:
162.36
EC號碼:
232-236-7
MDL號碼:
MFCD00011354
分類程式碼代碼:
12352300
PubChem物質ID:
329755974
NACRES:
NB.24
等級:
ACS reagent
形狀:
solid or liquid
溶解度:
acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)
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等級

ACS reagent

品質等級

200

形狀

solid or liquid

雜質

≤0.005% insolubles

bp

97.4 °C (lit.)

溶解度

acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)

密度

3.24 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

ClI

InChI

1S/ClI/c1-2

InChI 密鑰

QZRGKCOWNLSUDK-UHFFFAOYSA-N

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相關類別

一般說明

Iodine monochloride is an interhalogen compound.[1] It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated.[2] It affords electrically conducting solution on dissolution in polar solvents.[3] Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.[1]

應用

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes.[3] It may be used for the synthesis of flavones.[4]
Iodine monochloride may be used in the synthesis of the following:
  • 2-(4-haloisoquinolin-1-yl)ethanol derivatives[5]
  • 5-iodosalicylaldehydes[6]
  • 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines[7]
  • (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol[8]
  • (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol[8]

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險聲明

H314,H335

危險分類

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number
MKCX1629
MKCW0034
MKCL8779
MKCL8778
MKCL8776

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Ye S, et al.
Advanced Synthesis & Catalysis, 352(10), 1746-1751 (2010)
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Synthesis and Electrophilic Substitutions of Novel Pyrazolo [1, 5-c]-1, 2, 4-triazolo [4, 3-a] pyrimidines.
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Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for
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Questions

  1. what will be the normality if 10 ml of ICl diluted to 1800ml acetic acid

    1 answer

    1. Given that the ICl content of this product is approximately 90%, the calculated value is 0.10 N.
      Here is the calculation:
      (10 mL ICl / 1.800 LIters solution) X (3.24 grams ICl / 1 mL ICl) X (1 mole ICl / 162.36 g ICl) = 0.11 N.

      Please see the link below to review a sample Certificate of Analysis:
      https://www.sigmaaldrich.com/certificates/COFA/40/402990/402990-1KG-PW_____MKCL8779__.pdf

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