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重要文件

402826

Sigma-Aldrich

重铬酸铵

ACS reagent, ≥99.5%

同義詞:

红矾铵

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About This Item

線性公式:
(NH4)2Cr2O7
CAS號碼:
分子量::
252.06
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
eCl@ss:
38180716
PubChem物質ID:
NACRES:
NB.24
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等級

ACS reagent

品質等級

蒸汽密度

8.7 (vs air)

化驗

≥99.5%

形狀

crystals

反應適用性

reagent type: oxidant

雜質

≤0.005% insolubles

損耗

≤3.0% loss on drying

pH值

3-4 (25 °C, 50 g/L)

mp

170 °C (dec.) (lit.)

負離子痕跡

chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.01%

正離子痕跡

Ca: ≤0.002%
Fe: ≤0.002%
Na: ≤0.005%

SMILES 字串

N.N.O[Cr](=O)(=O)O[Cr](O)(=O)=O

InChI

1S/2Cr.2H3N.2H2O.5O/h;;2*1H3;2*1H2;;;;;/q2*+1;;;;;;;;;/p-2

InChI 密鑰

XAQCJVGGJJFLPP-UHFFFAOYSA-L

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一般說明

Ammonium dichromate is a hexavalent chromium compound with a high oxidation potential.[1] Hexavalent chromium is potent carcinogen and an environmental pollutant.[2]

應用

Ammonium dichromate may be used in the following processes:
  • Oxidation of alcohols in the presence of Mg(HSO4)2 (magnesium hydrogen sulfate) and wet SiO2 (silicon dixide).[3]
  • Preparation of Cr2O3/Al2O3 (chromium (III) oxide/aluminium oxide) catalysts.[4]
  • Oxidative coupling of thiols.[5]
  • Preparation of mesoporous molecular sieves.[6]
  • Preparation of polypyrrole (PPy).[7]
  • Preparation of solid oxide fuel cell (SOFC) interconnect.[8]

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

Hexavalent chromium (VI): Environment pollutant and health hazard.
Das AP and Mishra S.
Journal of Environmental Research And Development, 2(3), 386-392 (2008)
Oxidative coupling of thiols in solution and under solvent-free conditions.
Shirini F, et al.
Mendeleev Communications, 14(1), 34-35 (2004)
Oxidative dehydrogenation of propane over Cr2O3/Al2O3 and Cr2O3 catalysts: effects of loading, precursor and surface area.
Cherian M, et al.
Applied Catalysis A: General, 233(1), 21-33 (2002)
Oxidation of Alcohols by (NH4)2Cr2O7 in Solution and Under Solvent-Free Conditions.
Shirini F, et al.
Australian Journal of Chemistry, 54(6), 405-406 (2001)
Polypyrrole as a protective pigment in organic coatings
Selvaraj M, et al.
Synthetic Metals, 158(21), 888-899 (2008)

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