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238074

Sigma-Aldrich

乙酸铵

ACS reagent, ≥97%

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About This Item

線性公式:
CH3CO2NH4
CAS號碼:
分子量::
77.08
Beilstein:
4186741
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
eCl@ss:
39021908
PubChem物質ID:
NACRES:
NA.21
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等級

ACS reagent

蒸汽壓力

<0.001 hPa

化驗

≥97%

形狀

powder
solid

雜質

≤0.005% insolubles

燃燒殘留物

≤0.01%

pH值

6.7-7.3 (25 °C, 5%)

mp

110-112 °C (dec.) (lit.)

負離子痕跡

chloride (Cl-): ≤5 ppm
nitrate (NO3-): ≤0.001%
sulfate (SO42-): ≤0.001%

正離子痕跡

Fe: ≤5 ppm
heavy metals: ≤5 ppm

SMILES 字串

N.CC(O)=O

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

InChI 密鑰

USFZMSVCRYTOJT-UHFFFAOYSA-N

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相關類別

一般說明

乙酸铵(NH4CH3CO2,NH4OAc)是溶于水的吸湿性铵盐。它是环保型且价格低廉的化合物,可通过用冰醋酸与氨或碳酸铵反应来制备。它被用作催化剂以及有机合成中的氨源。

應用

乙酸铵可作为反应物和催化剂用于以下合成:      
  • 通过与2-萘酚和芳香醛的三组分缩合反应制备1,3-恶嗪衍生物。      
  • 用芳香醛和氰基乙酸乙酯处理的对称三联吡啶衍生物。      
  • 通过Pd催化的邻溴芳基醛和末端炔烃的连续偶联-亚胺化-成环反应生成异喹啉、呋喃并吡啶和噻吩并吡啶。

它还可以用作氮源,在Fe(III)−salen配合物作为催化剂的参与下,通过与儿茶酚和各种醛的多组分缩合反应来合成苯并噁唑衍生物。

特點和優勢

NH4OAc是一种环保、耐储存且安全的试剂。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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文章

Effective in key synthesis reactions like Knoevenagel condensation, thalidomide synthesis, and Suzuki coupling for sustainable chemical transformations.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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