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重要文件

202185

Sigma-Aldrich

氯化钴 六水合物

reagent grade

同義詞:

氯化钴 六水合物

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About This Item

線性公式:
CoCl2 · 6H2O
CAS號碼:
分子量::
237.93
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21
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等級

reagent grade

蒸汽壓力

40 mmHg ( 0 °C)

形狀

crystals or chunks

濃度

24.0-25.5% (EDTA titration)

SMILES 字串

O.O.O.O.O.O.Cl[Co]Cl

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI 密鑰

GFHNAMRJFCEERV-UHFFFAOYSA-L

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相關類別

一般說明

氯化钴 (II) 六水合物具有钴离子,被氯离子配体的四方排列包围。四个水分子占据了钴的正方形平面,而氯离子占据了轴向位置。[1]它的晶体属于单斜晶格系统。[2]

應用

氯化钴 (II) 六水合物可用于以下研究:
  • 用于原位 合成聚(4-苯乙烯磺酸-马来酸)稳定的镍 (0) 和钴 (0) 纳米簇。[3]
  • 静电纺丝法制备聚偏氟乙烯 (PVDF)-氯化钴 (II) 纳米纤维复合材料。[4]
  • 作为合成 2-芳基苯并咪唑的催化剂。[5]
  • 醇与羧酸乙酰化生成相应的的酰化产物。[6]
  • 脂肪醇和芳香醇与甲苯磺酸的甲苯磺酰化。[7]

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

Cobalt (II) catalyzed tosylation of alcohols with p-toluenesulfonic acid.
Velusamy S, et al.
Tetrahedron Letters, 45(1), 203-205 (2004)
Cobalt (II)-catalyzed direct acetylation of alcohols with acetic acid.
Velusamy S, et al.
Tetrahedron, 61(8), 2011-2015 (2005)
Crystal spectra of cobalt (II) chloride hexahydrate
Joy HW and Fogel N
The Journal of Physical Chemistry, 79(4), 345-349 (1975)
Electronic absorption spectra of tetragonal and pseudotetragonal cobalt (II). II. Cobalt chloride hexahydrate and cobalt chloride hexahydrate-d12.
Ferguson J and Wood TE.
Inorganic Chemistry, 14(1), 184-189 (1975)
Water soluble nickel (0) and cobalt (0) nanoclusters stabilized by poly (4-styrenesulfonic acid-co-maleic acid): highly active, durable and cost effective catalysts in hydrogen generation from the hydrolysis of ammonia borane.
Metin O and Ozkar S.
International Journal of Hydrogen Energy, 36(2), 1424-1432 (2011)

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Hi, Is this product suitable for cell culture? Thank you. Michal

    1 answer
    1. This item has not been tested for use in cell culture. However, a cell culture product option is available. Please see the link below to review product C8661: https://www.sigmaaldrich.com/US/en/product/sigma/c8661

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