推薦產品
等級
puriss.
化驗
≥98%
反應適用性
reagent type: catalyst
core: zinc
mp
394 °C (lit.)
負離子痕跡
sulfate (SO42-): ≤100 mg/kg
正離子痕跡
Ba: ≤10 mg/kg
Ca: ≤100 mg/kg
Fe: ≤10 mg/kg
K: ≤100 mg/kg
Mg: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
SMILES 字串
Br[Zn]Br
InChI
1S/2BrH.Zn/h2*1H;/q;;+2/p-2
InChI 密鑰
VNDYJBBGRKZCSX-UHFFFAOYSA-L
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一般說明
溴化锌是一种无机盐。负载在羟基磷灰石上的溴化锌(Zn-HAP)可促进3-取代吲哚的合成。
應用
溴化锌(ZnBr2)可用于以下研究:
- 从脱氧核苷中除去二甲氧基三苯甲基醚。
- 除去核苷衍生物中的N-酰基保护基。
- 不饱和酮和酯的O-甲硅烷基化二烯酸酯的烷基化。
- 作为催化剂用于合成α-全氟烷基化高烯丙醇。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
儲存類別代碼
8B - Non-combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。
The use of zinc bromide for removal of dimethoxytrityl ethers from deoxynucleosides.
Tetrahedron Letters, 31(34), 3243-3246 (1984)
Zinc bromide supported on hydroxyapatite as a new and efficient solid catalyst for Michael addition of indoles to electron-deficient olefins.
J. Mol. Catal. A: Chem., 246(1), 39-42 (2006)
Zinc bromide promoted allylation of aluminum acetals derived from perfluoro carboxylic acid esters and diisobutylaluminum hydride. New convenient access to a-perfluoroalkylated homoallyl alcohols.
Tetrahedron Letters, 34(36), 5777-5777 (1993)
γ-Alkylation of unsaturated ketones and esters: zinc bromide-catalysed alkylation of O-silylated dienolates.
Tetrahedron Letters, 20(34), 3209-3212 (1979)
Organic letters, 10(23), 5325-5328 (2008-11-05)
Kinetic studies using reaction calorimetry were conducted under synthetically relevant conditions to study the effect of additives in the cyanation of bromobenzene catalyzed by palladium complexes. This work demonstrates that the addition of a catalytic amount of ZnBr(2) facilitates the
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