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Merck
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文件

01132

Sigma-Aldrich

氟化钾

purified, ≥99%

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About This Item

線性公式:
KF
CAS號碼:
分子量::
58.10
Beilstein:
3902818
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

化驗

≥99%

形狀

crystalline

品質

purified

損耗

≤0.5% loss on ignition, 500 °C, 2 h

mp

858 °C (lit.)

負離子痕跡

chloride (Cl-): ≤100 mg/kg
sulfate (SO42-): ≤500 mg/kg

正離子痕跡

Fe: ≤50 mg/kg

SMILES 字串

[F-].[K+]

InChI

1S/FH.K/h1H;/q;+1/p-1

InChI 密鑰

NROKBHXJSPEDAR-UHFFFAOYSA-M

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一般說明

Potassium fluoride (KF) on activated alumina is a highly reactive catalyst (basic in nature) for various organic reactions. High reactivity is due to the formation of potassium hexafluoroaluminiate, potassium hydroxide and potassium aluminate on the interaction of its fluoride ion with alumina. Celite coated with potassium fluoride is an economical reagent for hydrogen-bond-assisted reactions. Potassium fluoride on basic alumina in acetonitrile with ultrasound has been employed for the deprotection of tert-butyldimethylsilyl ethers of phenols.

應用

Potassium fluoride may be employed for doping the natural calcium phosphate (NP) for high yield synthesis of activated alkenes.
用于研究两性聚合物凝胶的离子特异性溶胀和去溶胀的多功能氟离子源。贵金属在氟化氢中的室温氧化, 以及碱金属卤化物聚合物中离子的电子极化率的测量。

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Characterization of the actual catalytic agent in potassium fluoride on activated alumina systems.
Weinstock LM, et al.
Tetrahedron Letters, 27(33), 3845-3848 (1986)
Selective desilylation of tert-butyldimethylsilyl ethers of phenols using potassium fluoride-alumina and ultrasound.
Schmittling EA and Sawyer JS.
Tetrahedron Letters, 32(49), 7207-7210 (1991)
Natural phosphate doped with potassium fluoride and modified with sodium nitrate: Efficient catalysts for the Knoevenagel condensation.
Sebti S, et al.
Tetrahedron Letters, 43(10), 1813-1815 (2002)
Potassium fluoride on celite. A versatile reagent for C-, N-, O-, and S-alkylations.
Ando T and Yamawaki J.
Chemistry Letters (Jpn), 1, 45-46 (1979)

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