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62118

Supelco

(R)-(+)-柠檬烯

analytical standard

同義詞:

(+)-对薄荷-1,8-二烯, (+)-香芹烯, (R)-4-异丙烯基-1-甲基-1-环己烯

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About This Item

經驗公式(希爾表示法):
C10H16
CAS號碼:
分子量::
136.23
Beilstein:
2204754
EC號碼:
MDL號碼:
分類程式碼代碼:
85151701
PubChem物質ID:
NACRES:
NA.24
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等級

analytical standard

品質等級

蒸汽密度

4.7 (vs air)

蒸汽壓力

<3 mmHg ( 14.4 °C)

化驗

≥99.0% (sum of enantiomers, GC)

光學活性

[α]20/D +115.5±1°, c = 10% in ethanol

儲存期限

limited shelf life, expiry date on the label

expl. lim.

6.1 %

技術

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.473 (lit.)
n20/D 1.473

bp

176-177 °C (lit.)

密度

0.842 g/mL at 20 °C (lit.)

應用

agriculture
cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

形式

neat

儲存溫度

2-8°C

SMILES 字串

CC(=C)[C@@H]1CCC(C)=CC1

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1

InChI 密鑰

XMGQYMWWDOXHJM-JTQLQIEISA-N

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一般說明

(R)-(+)-柠檬烯是环状单萜柠檬烯的 R-和主要对映体。它是从橙子、葡萄柚和柠檬中提取的精油的主要成分。此外,它还作为调味剂添加到不同的个人和家庭清洁产品、饮料和糖果产品中。众所周知,它具有抗氧化、抗菌、抗真菌、抗炎和抗癌特性。[1][1]

應用

该分析标准也可按如下方式使用:
  • 采用两种新型电化学传感器的差分脉冲伏安法测定酒精饮料中的 (R)-(+)-柠檬烯
  • 采用二维高效液相色谱-电喷雾串联质谱法(ESI-MS/MS)同时测定 10 种香水产品样品中的柠檬烯和芳樟醇
  • 采用多维气相色谱-质谱联用技术测定柑橘属 3 种植物中挥发性手性化合物的对映体组成
  • 采用气相色谱-火焰离子化检测器(GC-FID)对野生和栽培茴香中挥发物和脂肪酸的多残留分析

其他說明

This compound is commonly found in plants of the genus: carum mentha salvia
环外双键的区域选择性加氢反应[2][3];桥环双键的区域选择性环氧化反应[4]

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

123.8 °F - closed cup

閃點(°C)

51 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

Rebecca Jordan et al.
Neuron, 98(6), 1214-1228 (2018-06-05)
The olfactory bulb (OB) is the first site of synaptic odor information processing, yet a wealth of contextual and learned information has been described in its activity. To investigate the mechanistic basis of contextual modulation, we use whole-cell recordings to
Whitefly attraction to rosemary (Rosmarinus officinialis L.) is associated with volatile composition and quantity
Sadeh D, et al.
PLoS ONE, 12(5) (2017)
Giuseppe Ferrandino et al.
Clinical and translational gastroenterology, 11(9), e00239-e00239 (2020-10-24)
Liver cirrhosis and its complication - hepatocellular carcinoma (HCC) - have been associated with increased exhaled limonene. It is currently unclear whether this increase is more strongly associated with the presence of HCC or with the severity of liver dysfunction.
R. Baker et al.
Journal of the Chemical Society. Chemical Communications, 414-414 (1987)
T. Kitahara et al.
Tetrahedron, 43, 2689-2689 (1987)

文章

A throughput HS-SPME-GC-MS method to analyze volatile compounds in Perilla leaves at low extraction temperatures using four different SPME fibers.

條款

GC Analysis of Sweet Orange Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

相關內容

Gas chromatography separates volatile compounds in the gas phase, applied in various industries for quality control.

氣相色譜法分離氣相中的揮發性化合物,應用於各行各業的品質控制。

Chromatograms

suitable for GC

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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