等級
purum
化驗
≥99.0% (RT)
形狀
solid
反應適用性
reagent type: catalyst
core: copper
mp
498 °C (lit.)
密度
4.77 g/mL at 25 °C (lit.)
SMILES 字串
Br[Cu]Br
InChI
1S/2BrH.Cu/h2*1H;/q;;+2/p-2
InChI 密鑰
QTMDXZNDVAMKGV-UHFFFAOYSA-L
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訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8B - Non-combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Robin B Bedford et al.
Dalton transactions (Cambridge, England : 2003), 39(43), 10464-10472 (2010-10-12)
The solvent-free, palladium-catalysed reaction of anilides with CuCl(2) in the presence or absence of copper acetate yields ortho-chlorinated anilides in good to excellent yields, even on a large scale (100 mmol). By contrast, the equivalent reactions with copper bromide, either
Yi-Si Feng et al.
Organic letters, 15(7), 1472-1475 (2013-03-12)
Cu-catalyzed decarboxylative alkynylation of quaternary α-cyano acetate salts with alkynyl bromides and alkynyl chlorides is described. This new reaction can be used for preparing functionalized butynenitrile derivatives.
Fei Yu et al.
The Journal of organic chemistry, 74(3), 1130-1134 (2009-01-07)
CuX(2)-mediated (X = Cl, Br) halolactonization of monoesters of 1,2-allenyl phosphonic acids is presented. The reaction proceeded smoothly under the mild condition for differently substituted allenic substrates giving the 4-halo-2,5-dihydro[1,2]oxaphosphole 2-oxides in good yields. The Suzuki cross-coupling reaction of these
Shengqing Ye et al.
Chemical communications (Cambridge, England), (36)(36), 5406-5408 (2009-09-03)
Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.
H Erguig et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(1), 133-136 (2000-03-23)
We have investigated the piezoreflectance spectra (deltaR/R) of the 1s Z12 exciton in single crystals of copper bromide CuBr at the temperature of 95 K with linearly polarized light. The spectra were successively studied with the pressure p along the
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