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30367

Sigma-Aldrich

1-丁基-3-甲基咪唑乙酸盐

≥96.0% (HPLC)

同義詞:

1-Butyl-3-methyl-1H-imidazol-3-ium acetate, 1-Methyl-3-butylimidazolium acetate

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About This Item

經驗公式(希爾表示法):
C10H18N2O2
CAS號碼:
分子量::
198.26
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥96.0% (HPLC)

形狀

liquid

雜質

≤1.0% water

SMILES 字串

CC([O-])=O.CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.C2H4O2/c1-3-4-5-10-7-6-9(2)8-10;1-2(3)4/h6-8H,3-5H2,1-2H3;1H3,(H,3,4)/q+1;/p-1

InChI 密鑰

BSKSXTBYXTZWFI-UHFFFAOYSA-M

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一般說明

1-Butyl-3-methylimidazolium acetate is a room temperature ionic liquid. It is reported to irreversibly adsorb gaseous CO2, therefore can be a useful means for the separation of greenhouse gas. CO2 has been reported to readily dissolve in 1-butyl-3-methylimidazolium-acetate. It also forms reversible molecular complex with CO2 in the ratio of 1 (CO2) : 2 (1-butyl-3-methylimidazolium-acetate).

應用

1-Butyl-3-methylimidazolium acetate may be used to effectively capture CO2 from post-combustion flue gas. It may be used in the preparation of 1-butyl-3-methylimidazolium-2-carboxylate via carboxylation with CO2.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

307.4 °F - closed cup

閃點(°C)

153.00 °C - closed cup

個人防護裝備

Eyeshields, Gloves


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分析證明 (COA)

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Carbon dioxide capture using ionic liquid 1-butyl-3-methylimidazolium acetate.
Shiflett MB, et al.
Energy and Fuels, 24(10), 5781-5789 (2010)
Laura E Barrosse-Antle et al.
Chemical communications (Cambridge, England), (25)(25), 3744-3746 (2009-06-27)
Gaseous CO(2) is almost irreversibly absorbed by the room temperature ionic liquid 1-butyl-3-methylimidazolium acetate ([C(4)mim][Ac]) in which it undergoes a chemically irreversible, one electron electrochemical reduction, suggesting a means for the sequestration of the greenhouse gas.
Marcel Besnard et al.
Chemical communications (Cambridge, England), 48(9), 1245-1247 (2011-12-14)
The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO(2) with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR ((1)H

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