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Merck
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重要文件

125733

Sigma-Aldrich

邻苯二甲酸酐

ReagentPlus®, 99%

同義詞:

1,2-Benzenedicarboxylic anhydride, 1,3-Isobenzofurandione, Phthalic acid anhydride

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About This Item

經驗公式(希爾表示法):
C8H4O3
CAS號碼:
分子量::
148.12
Beilstein:
118515
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.21
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蒸汽密度

5.1 (vs air)

品質等級

蒸汽壓力

<0.01 mmHg ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

flakes

自燃溫度

1058 °F

expl. lim.

10.4 %

bp

284 °C (lit.)

mp

131-134 °C (lit.)

官能基

anhydride
ester

SMILES 字串

O=C1OC(=O)c2ccccc12

InChI

1S/C8H4O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h1-4H

InChI 密鑰

LGRFSURHDFAFJT-UHFFFAOYSA-N

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一般說明

Phthalic anhydride is an industrially important chemical. It can be prepared from o-xylene or naphthalene.[1] It is widely used for the industrial preparation of plasticizers for PVC (polyvinyl chloride).[2]
Phthalic anhydride can be synthesized via oxidation of o-xylene, in the presence of V2O5/TiO2 monolithic catalyst supported by aluminium honeycomb.[3]

應用

Phthalic anhydride may be used in the synthesis of the following compounds:

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

305.6 °F - DIN 51758

閃點(°C)

152 °C - DIN 51758

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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"Conductive monolithic catalysts: development and industrial pilot tests for the oxidation of o-xylene to phthalic anhydride"
Groppi G, et al.
Industrial & Engineering Chemistry Research, 51(22), 7590-7596 (2011)
Phthalic anhydride from o-xylene catalysis: science and engineering.
Nikolov V, et al.
Catalysis Reviews: Science and Engineering, 33(3-4), 319-374 (1991)
Xin Hai et al.
Electrophoresis, 31(19), 3352-3361 (2010-10-01)
A rapid and sensitive electrophoretically mediated microanalysis method with field-enhanced sample injection (FESI) for in-capillary derivatization was developed to determine selenomethionine (SeMet) and selenomethionine selenoxide (SeOMet). Phthalic anhydride (PA) was selected as the derivatization reagent due to the fast reaction
C J Sparham et al.
Journal of chromatography. A, 1062(1), 39-47 (2005-02-01)
A new method for the analysis of alcohol ethoxylates (AEs) using electrospray ionisation liquid chromatography/mass spectrometry (ESI LC/MS) is described. The procedure incorporates a novel derivatisation step with phthalic anhydride for the analysis of EO0-20 ethoxylates in a single analysis.
A Micó-Tormos et al.
Journal of chromatography. A, 1203(1), 47-53 (2008-07-25)
The esterification of fatty alcohol ethoxylates (FAEs) with phthalic anhydride in 1,4-dioxane was studied. At 110 degrees C and in the presence of urea, which increased the reaction rate, esterification was completed in 60 min. The reaction yield did not

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