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重要文件

8.18823

Sigma-Aldrich

Sodium borohydride

(tablets) for synthesis

同義詞:

Sodium borohydride, Sodium tetrahydridoborate

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About This Item

經驗公式(希爾表示法):
H4BNa
CAS號碼:
分子量::
37.83
MDL號碼:
分類程式碼代碼:
12352306
酶委員會索引編號:
241-004-4
NACRES:
NA.22
暫時無法取得訂價和供貨情況

蒸汽壓力

<1 hPa ( 25 °C)

品質等級

形狀

solid

自燃溫度

220 °C

效力

160 mg/kg LD50, oral (Rat)
230 mg/kg LD50, skin (Rabbit)

expl. lim.

3.02 % (v/v)

反應適用性

reagent type: reductant

pH值

11 (20 °C, 10 g/L in H2O)

bp

500 °C (decomposition)

mp

>360 °C (slow decomposition)

轉變溫度

flash point 69 °C

密度

1.07 g/cm3 at 20 °C

體積密度

350‑500 kg/m3

儲存溫度

2-30°C

SMILES 字串

[Na][BH4]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI 密鑰

YOQDYZUWIQVZSF-UHFFFAOYSA-N

一般說明

Sodium borohydride (NaBH4) is the most commonly available borohydride used in several industrial applications. It is considered a selective reducing agent due to its ability to selectively reduce aldehydes and ketones into their corresponding alcohols in the presence of other functional groups such as nitro, ester, amide, lactone, epoxide, and nitriles. Ethanol and methanol are usually employed as solvents in NaBH4 reduction reactions.[1]

應用

Sodium borohydride (tablets form) can be used as a potential candidate to store as well as generate hydrogen for energy-carrier,applications.[2]

分析報告

Assay (hypochlorite): ≥ 96.0 %
Identity (ICP-OES): passes test

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

安全危害

儲存類別代碼

4.3 - Hazardous materials, which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Sodium Borohydride
Banfi Luca, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2014)
Hydrogen generation by both acidic and catalytic hydrolysis of sodium borohydride
Netskina OV, et al.
Catalysis for Sustainable Energy, 5(1), 41-48 (2018)

Questions

  1. Hi, there is no information on the properties of the tablets provided. How much does each tablet weigh? Are they 100% NaBH4, or do they contain any excipients? Are they provided in individual blister packs or in bulk?

    1 answer
    1. This product is a 6.35 mm diameter x 12.7 mm length caplet. The weight range per caplet is 0.98 - 1.02 g each. The minimum purity is 96% NaBH4. The identify of the impurities is not determined. Any excipient or binder components are considered proprietary. The caplets are package in glass bottles. Please note that this product is M-Clarity level MQ200 and is for R&D use only. Details regarding this grading system may be accessed at the link below:
      https://www.sigmaaldrich.com/US/en/life-science/quality-and-regulatory-management/m-clarity-program

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