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重要文件

8.14371

Sigma-Aldrich

三乙胺三氢氟酸

for synthesis

同義詞:

三乙胺三氢氟酸

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About This Item

線性公式:
(C2H5)3N · 3 HF
CAS號碼:
分子量::
161.21
MDL號碼:
分類程式碼代碼:
12352107
酶委員會索引編號:
277-550-5
NACRES:
NA.22
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品質等級

形狀

liquid

pH值

3 (20 °C in H2O, saturated aqueous solution)

bp

70 °C/19.9 hPa

轉變溫度

flash point 88 °C

密度

1.00 g/cm3 at 20 °C

儲存溫度

2-30°C

SMILES 字串

[F-].[F-].[F-].[N+H](CC)(CC)CC.[H+].[H+]

InChI

1S/C6H15N.3FH/c1-4-7(5-2)6-3;;;/h4-6H2,1-3H3;3*1H

InChI 密鑰

IKGLACJFEHSFNN-UHFFFAOYSA-N

應用

  • Asymmetric synthesis of fluoroamines from chiral aziridines:该文用三乙胺三氢氟酸盐合成氟胺类物质,它可提高反应选择性和效率(Park et al., 2014)。
  • Recent advance in the synthesis of (1, 1-difluoroethyl) arenes:该文讨论三乙胺三氢氟酸盐合成二氟乙基脂芳烃的最新进展,开发了新的氟化技术(Li et al., 2018)。
  • Quantification of hydrogen fluoride-based reagents using a bifunctional NMR internal standard:描述化学合成中三乙胺三氢氟酸盐等试剂的定量分析,检测方法具有准确性(Hammond et al., 2016)。
  • Extensive CRISPR RNA modification reveals chemical compatibility and structure-activity relationships for Cas9 biochemical activity:该研究用三乙胺三氢氟酸盐进行CRISPR-Cas9编辑的RNA修饰,说明它的基因工程作用(O′Reilly et al., 2019)。

分析報告

含量测定(HClO₄): ≥ 98.0 %
颜色(目测):无色、几乎无色
密度(d 20 °C/ 4 °C):0.995 - 1.000
鉴别(IR):符合检验

象形圖

CorrosionSkull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A

儲存類別代碼

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

190.4 °F

閃點(°C)

88 °C


分析證明 (COA)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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