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重要文件

P27127

Sigma-Aldrich

醋酸苯汞

97%

同義詞:

醋酸苯汞, 乙酸苯汞

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About This Item

線性公式:
C6H5HgOCOCH3
CAS號碼:
分子量::
336.74
Beilstein:
3662930
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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化驗

97%

形狀

powder

mp

148-151 °C (lit.)

SMILES 字串

CC(=O)O[Hg]c1ccccc1

InChI

1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1

InChI 密鑰

XEBWQGVWTUSTLN-UHFFFAOYSA-M

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應用

乙酸苯汞(PMA)可以与钯盐(例如乙酸钯)在原位反应形成芳基钯盐,然后与伯或仲烯丙醇反应生成3-芳基醛。[1]也可用于经Floyd′s途径多步合成2,3,4,6-四-O-乙酰基-α-D-吡喃葡萄糖基硫醇。[2]

免責聲明

For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

標靶器官

Kidney,Central nervous system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones.
Heck R F, et al.
Journal of the American Chemical Society, 90(20), 5526-5531 (1968)
Synthesis of aromatic and indole alpha-glucosinolates.
Vo Quan V, et al.
Carbohydrate Research, 455, 45-53 (2018)
Satu Lyyra et al.
Plant biotechnology journal, 5(2), 254-262 (2007-02-21)
Eastern cottonwood (Populus deltoides Bartr. ex Marsh.) trees were engineered to express merA (mercuric ion reductase) and merB (organomercury lyase) transgenes in order to be used for the phytoremediation of mercury-contaminated soils. Earlier studies with Arabidopsis thaliana and Nicotiana tabacum
C Grierson et al.
Analytical biochemistry, 404(2), 232-234 (2010-05-29)
The aim of this study was to combine matrix metalloproteinase-9 (MMP-9) protein (enzyme-linked immunosorbent assay [ELISA]) and MMP-9 activity (fluorescence resonance energy transfer [FRET] assay) data to generate units of specific activity in endogenous and p-aminophenylmercuric acetate (APMA)-activated lithium heparin
Lilla Landeck et al.
International journal of dermatology, 50(7), 806-810 (2011-06-28)
Some authors have claimed a decreased cell-mediated immunity among atopic individuals, which would lead to observations of decreased rates of allergic contact dermatitis (ACD). The purpose of our study was to investigate contact sensitization patterns in atopic subjects compared with

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