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Merck
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文件

M50001

Sigma-Aldrich

甲基肼

98%

同義詞:

MMH

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About This Item

線性公式:
CH3NHNH2
CAS號碼:
60-34-4
分子量：:
46.07
Beilstein:
635645
EC號碼:
200-471-4
MDL號碼:
MFCD00007621
分類程式碼代碼:
12352100
PubChem物質ID:
24896964
NACRES:
NA.22

蒸汽密度

1.6 (vs air)

蒸汽壓力

37.5 mmHg ( 20 °C)

化驗

98%

自燃溫度

385 °F

expl. lim.

97 %

折射率

n20/D 1.4325 (lit.)

bp

88-90 °C (lit.)

密度

0.875 g/mL at 20 °C (lit.)

SMILES 字串

CNN

InChI

1S/CH6N2/c1-3-2/h3H,2H2,1H3

InChI 密鑰

HDZGCSFEDULWCS-UHFFFAOYSA-N

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應用

甲基肼可用于诱导 β-三氟甲基-β,β-二取代烯酮的不对称需氧环氧化，合成对映选择性三氟甲基-取代的环氧化物。 也可用于合成1-甲基-3,5-二硝基-1H-1,2,4-三唑（DNMT），这是 TNT 炸药的替代物。

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

17.6 °F - closed cup

閃點（°C）

-8 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

分析證明 (COA)

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Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β, β-Disubstituted Enones.
Kawai H, et al.
Angewandte Chemie (International ed. in English), 125(8), 2277-2281 (2013)
A safe and scalable process for the synthesis of melt-cast explosive 1-methyl-3, 5-dinitro-1H-1, 2, 4-triazole.
Luo J, et al.
Chemistry of Heterocyclic Compounds, 53(6-7), 714-718 (2017)
J M Pujolar et al.
BMC genomics, 16, 600-600 (2015-08-14)
Species showing complex life cycles provide excellent opportunities to study the genetic associations between life cycle stages, as selective pressures may differ before and after metamorphosis. The European eel presents a complex life cycle with two metamorphoses, a first metamorphosis
Y I Kim et al.
The American journal of pathology, 149(4), 1129-1137 (1996-10-01)
Folate deficiency enhances colorectal carcinogenesis in dimethylhydrazine-treated rats. Folate is an important mediator of DNA methylation, an epigenetic modification of DNA that is known to be dysregulated in the early stages of colorectal cancer. This study investigated the effect of
M Runge-Morris et al.
Toxicology and applied pharmacology, 125(1), 123-132 (1994-03-01)
The hydrazines represent an important class of xenobiotic agents encountered in the environment, in industrial settings, and in medical therapeutics. Agents with a hydrazine functionality are metabolized to toxic intermediates capable of damaging cellular macromolecules and stimulating proteolysis. Phenylhydrazine (PH)
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