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重要文件

D38405

Sigma-Aldrich

2,4-二溴苯胺

98%

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About This Item

線性公式:
Br2C6H3NH2
CAS號碼:
分子量::
250.92
Beilstein:
2206653
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗

98%

形狀

crystals

mp

78-80 °C (lit.)

SMILES 字串

Nc1ccc(Br)cc1Br

InChI

1S/C6H5Br2N/c7-4-1-2-6(9)5(8)3-4/h1-3H,9H2

InChI 密鑰

DYSRXWYRUJCNFI-UHFFFAOYSA-N

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應用

2,4-Dibromoaniline can be used as:
  • A starting material to synthesize acetylenic amine by reacting with trimethylsilylacetylene, which is used as a ligand to prepare the bis-amido complex of Ti(IV).[1]
  • A substrate in the Pd-catalyzed ortho-selective cross-coupling reactions of dihaloarenes with Grignard reagents.[2]
  • A reactant to prepare dialkyl-substituted aminoaryl sulfides using a Grignard reagent.[3]
  • A starting material to synthesize substituted 2-mercapto benzimidazoles.[4]

象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Synthesis and crystal structure of (η5-C5H5)2 Ti(NH (2, 4-(C CSiMe3) 2C6H3)) 2
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Journal of Chemical Crystallography, 35(9), 673-677 (2005)
DHTP Ligands for the Highly Ortho-Selective, Palladium-Catalyzed Cross-Coupling of Dihaloarenes with Grignard Reagents: A Conformational Approach for Catalyst Improvement
Ishikawa S and Manabe K
Angewandte Chemie (International Edition in English), 122(4), 784-787 (2010)
Copper (I)-catalyzed synthesis of substituted 2-mercapto benzimidazoles
Murru S, et al.
The Journal of Organic Chemistry, 74(5), 2217-2220 (2009)
A facile one-pot preparation of alkyl aminoaryl sulfides for the synthesis of GW7647 as an agonist of peroxisome proliferator-activated receptor α
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