推薦產品
品質等級
化驗
98%
形狀
crystals
bp
195-197 °C (lit.)
mp
32-41 °C (lit.)
密度
0.958 g/mL at 25 °C (lit.)
SMILES 字串
O=C1CCCCCCC1
InChI
1S/C8H14O/c9-8-6-4-2-1-3-5-7-8/h1-7H2
InChI 密鑰
IIRFCWANHMSDCG-UHFFFAOYSA-N
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訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
165.2 °F
閃點（°C）
74 °C
個人防護裝備
Eyeshields, Gloves, type N95 (US)
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The total synthesis of asteriscanolide (1) has been achieved by taking advantage on an intermolecular Pauson-Khand cycloaddition and a ring-closing metathesis as key bond-forming transformations. The approach incorporates the cyclooctane stereogenic center prior to ring formation. Interestingly, the ring-closing metathesis
K Yamada et al.
Chemical & pharmaceutical bulletin, 45(12), 1898-1905 (1998-01-20)
Construction of the AB-ring system of the taxane framework via an A-ring annulation strategy was demonstrated by base-mediated intramolecular aldol reaction of (Z)-2,2-dimethyl-3-(1-methyl-2-oxopropylidene)cyclooctanone, affording the title compound, 1-hydroxy-8,11,11-trimethylbicyclo[5.3.1]undec-7-en-9-one. A cyclization precursor, the tetra-substituted (Z)-alkene, was prepared from the corresponding cyclooctanone
F E Harvey et al.
Brain research bulletin, 13(4), 541-547 (1984-10-01)
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The Journal of organic chemistry, 70(3), 973-981 (2005-01-29)
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Korany A Ali et al.
Archiv der Pharmazie, 345(3), 231-239 (2011-11-03)
The versatile synthon (E)-2-((dimethyl amino)methylene)cyclooctanone (2) was used as a key intermediate for the synthesis of cyclooctanones and cyclooctane-based heterocycles with pyrazole, isoxazole, pyrimidine, pyrazolopyrimidine, triazolopyrimidine and imidazopyrimidine derivatives via its reactions with several nitrogen nucleophiles. The newly synthesized compounds
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