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重要文件

ALD00618

Sigma-Aldrich

(+)-PI Reagent

≥95%

同義詞:

(2S,3aR,5S,7aR)-7a-methyl-2-((perfluorophenyl)thio)-5-(prop-1-en-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-sulfide, Phosphorus Incorporation reagent

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About This Item

經驗公式(希爾表示法):
C16H16F5OPS3
CAS號碼:
分子量::
446.46
MDL號碼:
分類程式碼代碼:
12352005
NACRES:
NA.22
暫時無法取得訂價和供貨情況

品質等級

化驗

≥95%

形狀

crystals

mp

119-124 °C

SMILES 字串

Fc1c(c(c(c(c1F)F)S[P]2(=S)S[C@H]3[C@](O2)(CC[C@@H](C3)C(=C)C)C)F)F

InChI

1S/C16H16F5OPS3/c1-7(2)8-4-5-16(3)9(6-8)25-23(24,22-16)26-15-13(20)11(18)10(17)12(19)14(15)21/h8-9H,1,4-6H2,2-3H3/t8-,9+,16+,23?/m0/s1

InChI 密鑰

CZCFCQOKUBIPHN-DWBMIXFYSA-N

應用

(+)-PI Reagent is an air- and moisture-tolerant, reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides. The enantiomer, (−)-PI Reagent, is also available.

Learn more about PI and PSI reagents

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Dongmin Xu et al.
Journal of the American Chemical Society, 142(12), 5785-5792 (2020-02-29)
Phosphorus Incorporation (PI, abbreviated Π) reagents for the modular, scalable, and stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides are reported. Synthesized from trans-limonene oxide, this reagent class displays an unexpected reactivity profile and enables access to chemical space distinct

文章

PI and PSI reagents are a platform of phosphate-based reagents for phosphorylation and phosphothiolation of nucleotides and peptides developed by the Baran lab.

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