ALD00600

Zhu-Yu Auxiliary

98%

• 同義詞: 1-Carboxy-1-methylethoxyammonium chloride, 2,2-Dimethyl aminooxyacetic, 2-(Aminooxy)-2-methylpropanoic acid hydrochloride
• 經驗公式（希爾表示法）: C₄H₁₀ClNO₃
• CAS號碼: 89766-91-6
• 分子量：: 155.58
• MDL號碼: MFCD08063911
• 分類程式碼代碼: 12352101

屬性

• 化驗: 98%
• 形狀: powder or crystals
• 反應適用性: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• 存貨情形: available only in USA
• mp: 150-165 °C
• SMILES 字串: [Cl-].NOC(C)(C)C(=O)O.[H+]
• InChI: 1S/C4H9NO3.ClH/c1-4(2,8-5)3(6)7;/h5H2,1-2H3,(H,6,7);1H
• InChI 密鑰: ZJPZGAAOCIFBDI-UHFFFAOYSA-N

描述

應用

The Zhu-Yu Auxiliary was reported by Jin-Quan Yu′s lab to be an effective auxiliary for the Pd(II)-catalyzed ß-C(sp3)-H(hetero)arylation of ketones.

其他說明

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via ß-C(sp3)-H Activation

安全資訊

• 象形圖: GHS02
• 訊號詞: Danger
• 危險聲明: H242
• 防範說明: P210 - P234 - P235 - P240 - P370 + P378 - P403
• 危險分類: Self-react. C
• 儲存類別代碼: 5.2 - Organic peroxides and self-reacting hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable