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Merck
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重要文件

ALD00578

Sigma-Aldrich

2-Bromopyridin-3-yl sulfurofluoridate

95%

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About This Item

經驗公式(希爾表示法):
C5H3BrFNO3S
分子量::
256.05
分類程式碼代碼:
12352200
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

95%

形狀

liquid

折射率

n20/D 1.5160

轉變溫度

flash point >230 °F

密度

1.8283 g/mL

儲存溫度

2-8°C

應用

2-Bromopyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences.

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3


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文章

This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.

相關內容

The Sharpless Lab pursues useful new reactivity and general methods for selectively controlling chemical reactions.

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