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Merck
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文件

A6057

Sigma-Aldrich

4-叠氮苯甲酰甲基溴

powder

同義詞:

4-叠氮-α-溴苯乙酮, 4′-叠氮-2-溴苯乙酮

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About This Item

經驗公式(希爾表示法):
C8H6BrN3O
CAS號碼:
分子量::
240.06
Beilstein:
1961705
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

形狀

powder

反應適用性

reaction type: click chemistry
reagent type: cross-linking reagent

顏色

yellow

溶解度

methanol: 50 mg/mL

儲存溫度

2-8°C

SMILES 字串

BrCC(=O)c1ccc(cc1)N=[N+]=[N-]

InChI

1S/C8H6BrN3O/c9-5-8(13)6-1-3-7(4-2-6)11-12-10/h1-4H,5H2

InChI 密鑰

LZJPDRANSVSGOR-UHFFFAOYSA-N

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應用

光敏双异官能化交联剂。通常,初始反应在 7.0-8.0 的 pH 范围内偶联巯基。然后在紫外光 (250nm) 的照射下通过反应性氮烯发生二次键合。后一步的键合快速并且具有非特异性。

注意

还原剂(如硫醇)可将叠氮化物还原为胺类,所以应当避免还原剂出现在反应中。初始操作和偶联反应应当在弱光照条件下进行。

訊號詞

Danger

危險分類

Eye Dam. 1 - Flam. Sol. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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