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重要文件

A32608

Sigma-Aldrich

烯丙基缩水甘油醚

≥99%

同義詞:

1-烯丙氧基-2,3-环氧丙烷, 烯丙基-2,3-环氧丙醚

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About This Item

經驗公式(希爾表示法):
C6H10O2
CAS號碼:
分子量::
114.14
Beilstein:
105871
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23
暫時無法取得訂價和供貨情況

蒸汽密度

3.9 (vs air)

品質等級

蒸汽壓力

4.7 mmHg ( 25 °C)

化驗

≥99%

形狀

liquid

折射率

n20/D 1.433 (lit.)

bp

154 °C (lit.)

密度

0.962 g/mL at 25 °C (lit.)

SMILES 字串

C=CCOCC1OC1

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

InChI 密鑰

LSWYGACWGAICNM-UHFFFAOYSA-N

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一般說明

烯丙基缩水甘油醚(AGE)可作为聚(烯丙基缩水甘油醚)阴离子开环聚合反应的合成单体。它在工业上可以通过烯丙醇和环氧氯丙烷反应制备而成。[1][2]

應用

AGE可用作氢化硅烷化制备粘附性表面的末端环氧基团。[3]它还可用于合成锂电池用聚电解质。[4]
用于氢化硅烷化,包括H2PtCl6·xH2O(货号206083)催化的硅氧烷成为环氧硅氧烷的氢化硅烷化。[5]

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

134.6 °F - closed cup

閃點(°C)

57 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Bhalchandra K Vaidya et al.
Bioresource technology, 99(9), 3623-3629 (2007-09-04)
Macroporous polymer particles containing surface epoxy groups were synthesized for immobilization of Candida rugosa lipase (CRL). The effect of incorporation of two different sets of monomers [allyl glycidyl ether (AGE) and glycidyl methacrylate (GMA)] and the effect of crosslinking density
Challa Lahari et al.
Langmuir : the ACS journal of surfaces and colloids, 26(2), 1096-1106 (2009-12-10)
Effects of changes in hydrophobicity of polymeric support on structure and activity of alpha-chymotrypsin (E.C. 3.4.21.1) have been studied with copolymers of allyl glycidyl ether (AGE) and ethylene glycol dimethacrylate (EGDM) with increasing molar ratio of EGDM to AGE (cross-link
A Dooms-Goossens et al.
Contact dermatitis, 33(1), 17-19 (1995-07-01)
We present a 43-year-old man who worked in the plastics industry and who suffered from an occupational dermatitis on the hands and forearms. He was found to be allergic to an epoxy silane compound that was contaminated with allyl glycidyl
Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries
Barteau KP, et al.
Macromolecules, 46(22), 8988-8994 (2013)
Y Koyama et al.
Bioconjugate chemistry, 7(3), 298-301 (1996-05-01)
Novel poly(ethylene glycol) (PEG) derivatives having pendant amino groups were prepared by copolymerization of allyl glycidyl ether with ethylene oxide followed by chemical modification of the double bond side chains. Dropwise addition of the mixture of monomers to the anionic

文章

Discussion of synthetic modifications to gelatin, improving the three-dimensional (3D) print resolution, and resulting material properties.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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