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919365

Sigma-Aldrich

(MeBPI)Ni-OAc

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About This Item

經驗公式（希爾表示法）:
C22H19N5NiO2
分子量：:
444.11
分類程式碼代碼:
12352200
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

powder

品質等級

100

反應適用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

相關類別

應用

(MeBPI)Ni-OAc is a Ni catalyst developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with a redox-active shuttle (918105), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

其他說明

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

相關產品

產品號碼
描述
訂價

918105

(MeBPI)2Ni, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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