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重要文件

907847

Sigma-Aldrich

HB(trip)2

≥95%

同義詞:

Bis(2,4,6-triisopropylphenyl)borane

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About This Item

經驗公式(希爾表示法):
C30H47B
CAS號碼:
分子量::
418.51
MDL號碼:
分類程式碼代碼:
12352101
NACRES:
NA.22
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化驗

≥95%

形狀

solid

mp

109-110 °C

儲存溫度

−20°C

SMILES 字串

B(c2c(cc(cc2C(C)C)C(C)C)C(C)C)c1c(cc(cc1C(C)C)C(C)C)C(C)C

InChI

1S/C30H47B/c1-17(2)23-13-25(19(5)6)29(26(14-23)20(7)8)31-30-27(21(9)10)15-24(18(3)4)16-28(30)22(11)12/h13-22,31H,1-12H3

InChI 密鑰

YGFOJGHLKBDBDV-UHFFFAOYSA-N

應用

HB(trip)2 has been shown by the Hoveyda group to be a useful traceless protecting group for catalytic Z- and E-selective olefin metathesis.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

Lot/Batch Number

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Yucheng Mu et al.
Angewandte Chemie (International ed. in English), 58(16), 5365-5370 (2019-02-13)
An operationally simple in situ protection/deprotection strategy that significantly expands the scope of kinetically controlled catalytic Z- and E-selective olefin metathesis is introduced. Prior to the addition of a sensitive Mo- or Ru-based complex, treatment of a hydroxy- or a

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