900715

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

• 同義詞: Chiral MPAO ligand
• 經驗公式（希爾表示法）: C₂₃H₂₈N₂O₂
• CAS號碼: 2079094-32-7
• 分子量：: 364.48
• 分類程式碼代碼: 12161600
• NACRES: NA.22

屬性

• 化驗: ≥95%
• 形狀: powder or crystals
• 反應適用性: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 130 °C
• 官能基: amide; phenyl
• 儲存溫度: 2-8°C

描述

應用

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide is a chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp³)H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

其他說明

Formation of α-chiral centers by asymmetric β-C(sp³)–H arylation, alkenylation, and alkynylation

安全資訊

• 危險聲明: H413
• 危險分類: Aquatic Chronic 4
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable