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Merck
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文件

806501

Sigma-Aldrich

Boc-Thr(tBu)-OH

同義詞:

N-叔丁氧羰基-O-叔丁基-L-苏氨酸

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About This Item

線性公式:
(CH3)3COCH(CH3)CH(COOH)NHCOOC(CH3)3
CAS號碼:
分子量::
275.34
Beilstein:
4454820
MDL號碼:
分類程式碼代碼:
12352209
PubChem物質ID:
NACRES:
NA.22

化驗

95%

品質等級

形狀

powder

mp

98.9 °C

應用

peptide synthesis

儲存溫度

2-8°C

SMILES 字串

C[C@@H](OC(C)(C)C)[C@H](NC(=O)OC(C)(C)C)C(O)=O

InChI

1S/C13H25NO5/c1-8(18-12(2,3)4)9(10(15)16)14-11(17)19-13(5,6)7/h8-9H,1-7H3,(H,14,17)(H,15,16)/t8-,9+/m1/s1

InChI 密鑰

LKRXXARJBFBMCE-BDAKNGLRSA-N

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一般說明

Boc-Thr(t-Bu)-OH (N-Boc-O-tert-butyl-L-threonine) participates in the synthesis of 2,3-unsaturated glycosides, via reaction with per-O-acetylated glucal in the presence of Er(OTf)3 catalyst.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Antonio Procopio et al.
Carbohydrate research, 342(14), 2125-2131 (2007-06-23)
Er(OTf)(3) is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transformation has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be
Christian Haenig et al.
Cell reports, 32(7), 108050-108050 (2020-08-20)
Interactome maps are valuable resources to elucidate protein function and disease mechanisms. Here, we report on an interactome map that focuses on neurodegenerative disease (ND), connects ∼5,000 human proteins via ∼30,000 candidate interactions and is generated by systematic yeast two-hybrid

相關內容

The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.

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