805041

2-(三甲硅基)-2-环己烯-1-酮

• 經驗公式（希爾表示法）: C₉H₁₆OSi
• CAS號碼: 72162-99-3
• 分子量：: 168.31
• MDL號碼: MFCD11502410
• 分類程式碼代碼: 12352100
• PubChem物質ID: 329768917
• NACRES: NA.22

屬性

• 描述: Fp: 15.8°F
• 品質等級: 100
• 形狀: liquid
• 折射率: n20/D 1.4524
• 密度: 0.8680 g/mL at 25 °C
• 官能基: ketone
• 儲存溫度: −20°C
• SMILES 字串: O=C1C([Si](C)(C)C)=CCCC1
• InChI: 1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
• InChI 密鑰: SXGCQSJRVVKTOH-UHFFFAOYSA-N

描述

一般說明

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

應用

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

其他說明

Cycloadditions of Cyclohexynes and Cyclopentyne

Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs

安全資訊

• 象形圖: GHS02,GHS07
• 訊號詞: Warning
• 危險聲明: H228,H302
• 防範說明: P210 - P301 + P312 + P330 - P370 + P378
• 危險分類: Acute Tox. 4 Oral - Flam. Sol. 2
• 儲存類別代碼: 4.1B - Flammable solid hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 15.8 °F
• 閃點（°C）: -9 °C