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775118

Sigma-Aldrich

硼烷二甲基硫醚络合物 溶液

greener alternative

1.0 M in 2-methyltetrahydrofuran

同義詞:

BMS, 三氢 [硫代双 [甲烷]] 硼

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About This Item

線性公式:
(CH3)2S · BH3
CAS號碼:
分子量::
75.97
Beilstein:
3663489
MDL號碼:
分類程式碼代碼:
12352112
PubChem物質ID:
NACRES:
NA.22
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形狀

liquid

反應適用性

reagent type: reductant

環保替代產品特色

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

濃度

1.0 M in 2-methyltetrahydrofuran

密度

0.844 g/mL at 25 °C

官能基

thioether

環保替代類別

儲存溫度

2-8°C

SMILES 字串

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI 密鑰

RMHDLBZYPISZOI-UHFFFAOYSA-N

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一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

應用

用作区域选择性还原剂的反应物

涉及的反应物:
  • 硼氢化/氧化
笼状化合物的合成
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane

包裝

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 2

閃點(°F)

9.3 °F

閃點(°C)

-12.6 °C


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