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760110

Sigma-Aldrich

4-氰基-4-[(十二烷基磺胺基硫代羰基)磺胺基]戊醇

4-Cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanol

同義詞:

十二烷基硫醇氰基硫醇

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About This Item

經驗公式（希爾表示法）:
C19H35NOS3
分子量：:
389.68
MDL號碼:
MFCD22417215
分類程式碼代碼:
12162002
PubChem物質ID:
329766838
NACRES:
NA.23
暫時無法取得訂價和供貨情況

化驗

≥96.5% (HPLC)

品質等級

100

形狀

solid or liquid (Powder or Solid or Crystals or Chunk(s) or Semi-solid or Liquid)

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SC(C)(CCCO)C#N

InChI

1S/C19H35NOS3/c1-3-4-5-6-7-8-9-10-11-12-16-23-18(22)24-19(2,17-20)14-13-15-21/h21H,3-16H2,1-2H3

InChI 密鑰

SAFBIHFUHZPVOZ-UHFFFAOYSA-N

相關類別

一般說明

可逆加成-断裂链转移（RAFT）聚合是一种制备窄分布复杂结构聚合物的方法。4-氰基-4-[（十二烷基磺酰基硫代羰基）磺酰基] 戊醇是一种羟基官能化三硫代碳酸盐筏试剂。[1]用作 RAFT 和开环聚合的双引发剂，以形成明确定义的嵌段共聚物。它们能很好地控制各种乙烯基单体的聚合。[2]

應用

嵌段共聚物 RAFT 和开环聚合的引发剂—这些嵌段共聚物来自于乙烯、金属离子、丙烯酰胺和环状单体的乙烯单体。[2]

特點和優勢

水解稳定性好，适用于各种单体及反应条件。[2]

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險聲明

H301

危險分類

Acute Tox. 3 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

No data available

閃點（°C）

No data available

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCT7968
MKCQ3678
MKCK9881
MKCF4022
MKBW0041V

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Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

文章

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

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Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

透過 RAFT 進行聚合的典型程序

本文介紹 CSIRO 研究人員聚合甲基丙烯酸甲酯和醋酸乙烯酯均聚物及嵌段共聚物的程序。

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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相關內容

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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我們的科學家團隊在所有研究領域都有豐富的經驗，包括生命科學、材料科學、化學合成、色譜、分析等.

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