699918
(R)-N-[(1R,2R)-2-(3-(3,5-双(三氟甲基)苯基)脲基)环己基]-叔丁基亚磺酰胺
96%
同義詞:
[S(R)]-N-[(1R,2R)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]carbonyl]amino]cyclohexyl]-2-methyl-2-propanesulfinamide
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About This Item
經驗公式（希爾表示法）:
C19H25F6N3O2S
CAS號碼:
分子量：:
473.48
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22
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化驗
96%
形狀
solid
mp
173-181 °C
SMILES 字串
CC(C)(C)S(=O)N[C@@H]1CCCC[C@H]1NC(=O)Nc2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI
1S/C19H25F6N3O2S/c1-17(2,3)31(30)28-15-7-5-4-6-14(15)27-16(29)26-13-9-11(18(20,21)22)8-12(10-13)19(23,24)25/h8-10,14-15,28H,4-7H2,1-3H3,(H2,26,27,29)/t14-,15-,31-/m1/s1
InChI 密鑰
WMIJNZVQFOPOBW-ZHANGXNJSA-N
應用
(R)-N-[(1R,2R)-2-(3-(3,5-Bis(trifluoromethyl)phenyl)ureido)cyclohexyl]-tert-butyl-sulfinamide is a sulfinamide-urea based chiral catalyst that can be used to synthesize:
- Enantioselective homoallylic amines by asymmetric allylation of acylhydrazones with allylindium reagents.
- Tetrahydroquinolines via an asymmetric Povarov reaction.
- 2-aryl-substituted cycloalkanones by enantioselective protonation of corresponding trimethylsilyl enol ethers.
危險聲明
危險分類
Aquatic Chronic 4
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
客戶也查看了
Indium-mediated asymmetric allylation of acylhydrazones using a chiral urea catalyst.
Kian L Tan et al.
Angewandte Chemie (International ed. in English), 46(8), 1315-1317 (2007-01-11)
Elizabeth M Beck et al.
Organic letters, 13(16), 4260-4263 (2011-07-27)
The application of chiral sulfinamides and achiral sulfonic acids as a cocatalyst system for enantioselective protonation reactions is described. Structurally simple, easily accessible sulfinamides were found to induce moderate-to-high ee's in the formation of 2-aryl-substituted cycloalkanones from the corresponding trimethylsilyl
Baudouin Gerard et al.
ACS combinatorial science, 14(11), 621-630 (2012-10-24)
A 2328-membered library of 2,3,4-trisubstituted tetrahydroquinolines was produced using a combination of solution- and solid-phase synthesis techniques. A tetrahydroquinoline (THQ) scaffold was prepared via an asymmetric Povarov reaction using cooperative catalysis to generate three contiguous stereogenic centers. A matrix of
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