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682675

Sigma-Aldrich

2-异丁酰基环己酮

96%

同義詞:

2-(2-甲基-1-氧代丙烷)环己酮

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About This Item

經驗公式(希爾表示法):
C10H16O2
CAS號碼:
分子量::
168.23
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22

化驗

96%

形狀

liquid

反應適用性

reagent type: ligand

折射率

n20/D 1.5006

密度

1.0076 g/mL at 25 °C

官能基

ketone

SMILES 字串

CC(C)C(=O)C1CCCCC1=O

InChI

1S/C10H16O2/c1-7(2)10(12)8-5-3-4-6-9(8)11/h7-8H,3-6H2,1-2H3

InChI 密鑰

PFOYYSGBGILOQZ-UHFFFAOYSA-N

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

219.9 °F - closed cup

閃點(°C)

104.4 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Zhiyu Jia et al.
Angewandte Chemie (International ed. in English), 53(42), 11298-11301 (2014-09-10)
The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of a 2-iodoaryl group. The
Yoshihide Usami et al.
Molecules (Basel, Switzerland), 25(20) (2020-10-16)
Alkylamino coupling reactions at the C4 positions of 4-halo-1H-1-tritylpyrazoles were investigated using palladium or copper catalysts. The Pd(dba)2 catalyzed C-N coupling reaction of aryl- or alkylamines, lacking a β-hydrogen atom, proceeded smoothly using tBuDavePhos as a ligand. As a substrate

文章

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

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