推薦產品
反應適用性
reaction type: Grignard Reaction
濃度
0.7 M in diethyl ether/hexanes
密度
0.769 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
[Li+].CCCC[Mg-](CCCC)CCCC
InChI
1S/3C4H9.Li.Mg/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;/q;;;+1;-1
InChI 密鑰
MYNWCAJLXIFFBO-UHFFFAOYSA-N
一般說明
Tri-n-butyllithium magnesate is a base and deprotonating agent used in the deprotonation of furans, fluoro aromatics, thiophenes, oxazoles and benzoxazoles.
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
-13.0 °F
閃點（°C）
-25 °C
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Deprotonation of benzoxazole and oxazole using lithium magnesates
Bayh O, et al.
The Journal of Organic Chemistry, 70(13), 5190-5196 (2005)
Deprotonation of thiophenes using lithium magnesates
Bayh O, et al.
Tetrahedron, 61(20), 4779-4784 (2005)
Deprotonation of furans using lithium magnesates
Mongin F, et al.
Tetrahedron Letters, 46(46), 7989-7992 (2005)
Deprotonation of fluoro aromatics using lithium magnesates.
Awad H, et al.
Tetrahedron Letters, 45(36), 6697-6701 (2004)
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