642629

二叔丁基甲膦

97%

• 同義詞: (t-Bu)2PMe, Bis(tert-butyl)methylphosphine
• 線性公式: [(CH₃)₃C]₂PCH₃
• CAS號碼: 6002-40-0
• 分子量：: 160.24
• MDL號碼: MFCD11869304
• 分類程式碼代碼: 12352001
• PubChem物質ID: 24883212

屬性

• 品質等級: 100
• 化驗: 97%
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• bp: 58 °C/12 mmHg (lit.)
• 密度: 0.824 g/mL at 25 °C (lit.)
• 官能基: phosphine
• SMILES 字串: CP(C(C)(C)C)C(C)(C)C
• InChI: 1S/C9H21P/c1-8(2,3)10(7)9(4,5)6/h1-7H3
• InChI 密鑰: JURBTQKVGNFPRJ-UHFFFAOYSA-N

描述

應用

在交叉偶联催化反应中与多种钯复合物一起使用的大体积膦。[1]

Di-tert-butylmethylphosphine (P^tBu₂Me) when added as HBF₄ salt, enhances the reactivity of palladium-catalyzed direct arylation of heterocylic arenes with aryl chlorides, bromides[2] and azine N-oxides with aryl triflates to form the corresponding biaryl and 2-aryl azine N-oxides, respectively.[3] It may be used in the preparation of CoCl₂(PtBu₂Me)₂, a cobalt phosphine complex, which in combination with methylaluminoxane (MAO) catalyzes the butadiene polymerization to form predominantly the cis-1,4 polymer.[4]

安全資訊

• 象形圖: GHS02,GHS05
• 訊號詞: Danger
• 危險聲明: H250,H314
• 防範說明: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• 危險分類: Pyr. Liq. 1 - Skin Corr. 1B
• 儲存類別代碼: 4.2 - Pyrophoric and self-heating hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter