推薦產品
化驗
97%
形狀
solid
mp
139-143 °C (lit.)
SMILES 字串
O=Cc1cccc2[nH]ccc12
InChI
1S/C9H7NO/c11-6-7-2-1-3-9-8(7)4-5-10-9/h1-6,10H
InChI 密鑰
JFDDFGLNZWNJTK-UHFFFAOYSA-N
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一般說明
Indole-4-carboxaldehyde participates in the synthesis of arcyriacyanin A. Synthesis of 4-indole-4-carboxaldehyde has been reported. Intramolecular Friedel-Crafts (FC) acylation of indole-4-carboxaldehyde has been reported.
應用
- reactant in Biginelli reaction
- reactant in synthesis of aurora kinase A inhibitors
- reactant in preparation of antitumor agents
- reactant in intramolecular Friedel-Crafts acylation
- reactant in preparation of inhibitors of cell division in E. coli
- reactant in synthesis of Hantzsch pyridine-containing Schiff bases
訊號詞
Warning
危險聲明
危險分類
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
Synthesis of Fused 4, 5-Disubstituted Indole Ring Systems by Intramolecular Friedel-Crafts Acylation of 4-Substituted Indoles.
Fillion E and Dumas AM.
The Journal of Organic Chemistry, 73(7), 2920-2923 (2008)
Total syntheses of clavine alkaloids by an intramolecular nitrone-olefin cycloaddition reaction.
Oppolzer W, et al.
Tetrahedron, 39(22), 3695-3705 (1983)
George A Kraus et al.
Organic letters, 10(14), 3061-3063 (2008-06-25)
The reaction of (2-aminobenzyl) triphenylphosphonium bromide with aromatic aldehydes or alpha,beta-unsaturated aldehydes under microwave-assisted conditions constitutes a new synthesis of 2-substituted indoles in high yields (81-97%) in a one-pot reaction. The adduct from indole-4-carboxaldehyde was an advanced intermediate in the
Synthesis of (-)-chanoclavine I.
Kardos N and Genet J-P.
Tetrahedron Asymmetry, 5(8), 1525-1533 (1994)
A New Synthesis method of indole-4-carboxaldehyde.
Wu Y-M, et al.
He Cheng Hua Xue / Chinese Journal of Synthetic Chemistry, 12, 333-335 (2004)
文章
在 Lewis 酸催化劑的作用下，Friedel-Crafts 醯化作用可透過親電芳香取代鹵素形成單醯化產品。
Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.
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