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重要文件

60811

Sigma-Aldrich

羰基钴

moistened with hexane (hexane 1-10%), ≥90% (Co)

同義詞:

八羰基二钴

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About This Item

線性公式:
Co2(CO)8
CAS號碼:
分子量::
341.95
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
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化驗

≥90% (Co)

形狀

solid

品質

moistened with hexane (hexane 1-10%)

反應適用性

core: cobalt
reagent type: catalyst

儲存溫度

2-8°C

SMILES 字串

[Co++].[Co++].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2

InChI 密鑰

MQIKJSYMMJWAMP-UHFFFAOYSA-N

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應用

  • 八羰基二钴[Co2(CO)8]常用于催化烯烃的加氢甲酰化反应(羰化反应)。[1][2]
  • 它与吡啶一起,可催化烯烃的羧化反应,产生相应的酸和酯。[1]
  • 它被用作制备钴铂(CoPt3)、硫化钴(Co3S4)和硒化钴(CoSe2)纳米晶体的关键前体。[3][4]
  • 它还被用作Pauson-Khand环化反应和Nicholas反应的试剂。[5][6]

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Repr. 2 - Self-heat. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation

標靶器官

Nervous system

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

-9.4 °F

閃點(°C)

-23 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

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M Varón et al.
Scientific reports, 3, 1234-1234 (2013-02-08)
Magnetostatic (dipolar) interactions between nanoparticles promise to open new ways to design nanocrystalline magnetic materials and devices if the collective magnetic properties can be controlled at the nanoparticle level. Magnetic dipolar interactions are sufficiently strong to sustain magnetic order at
A Lewis acid-mediated version of the Nicholas reaction: Synthesis of syn-alkylated products and cobalt-complexed cycloalkynes.
Schreiber SL, et al.
Journal of the American Chemical Society, 108(11), 3128-3130 (1986)
Octacarbonyldicobalt.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-26 (2014)
Eirini Zacharaki et al.
Chemistry Central journal, 10, 10-10 (2016-03-10)
Reproducible growth of narrow size distributed ε-Co nanoparticles with a specific size requires full understanding and identification of the role of essential synthesis parameters for the applied synthesis method. For the hot injection methodology, a significant discrepancy with respect to
Gaoxiang Liu et al.
Chemical science, 10(6), 1760-1766 (2019-03-08)
Molecular clusters are attractive superatomic building blocks for creating materials with tailored properties due to their unique combination of atomic precision, tunability and functionality. The ligands passivating these superatomic clusters offer an exciting opportunity to control their electronic properties while

文章

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Is this packed under inert gas?

    1 answer
    1. Yes, this product is packaged under an inert gas as a precautionary measure. Additionally, since it is sensitive to air, it should be handled and stored under an inert gas.

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