567159

1,1′-双(苯基亚膦基)二茂铁

97%

• 同義詞: 1,1′-(二茂铁二基)苯膦
• 線性公式: C₅H₄PC₆H₅C₅H₄Fe
• CAS號碼: 72954-06-4
• 分子量：: 292.09
• MDL號碼: MFCD04974069
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24880349
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: solid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 88-92 °C (lit.)
• 官能基: phosphine
• 儲存溫度: 2-8°C
• SMILES 字串: [Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
• InChI: 1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
• InChI 密鑰: HKOUDNXXOXEYNZ-UHFFFAOYSA-N

描述

應用

Reactant for:

• Preparation of macrocyclic tridentate ferrocenylphosphine ligands
• Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
• Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
• Ring-opening reactions via ring slippage
• Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)