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50 ML
About This Item
線性公式:
Cl2C6H3MgBr
CAS號碼:
分子量::
250.20
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
推薦產品
反應適用性
reaction type: Grignard Reaction
品質等級
濃度
0.5 M in THF
bp
65 °C
密度
0.972 g/mL at 25 °C
官能基
chloro
儲存溫度
2-8°C
SMILES 字串
Clc1cc(Cl)cc([Mg]Br)c1
InChI
1S/C6H3Cl2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1
InChI 密鑰
PWOVECVCCCTJFQ-UHFFFAOYSA-M
應用
3,5-Dichlorophenylmagnesium bromide can be used:
- In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene.[1]
- As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates.[2]
- As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand.[3]
法律資訊
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
-6.2 °F - closed cup
閃點(°C)
-21.2 °C - closed cup
Addition of Grignard reagents to aryl acid chlorides: an efficient synthesis of aryl ketones
Wang X, et al.
Organic Letters, 7(25), 5593-5595 (2005)
Toward Singlet-Triplet Bistable Nonalternant Kekule? Hydrocarbons: Azulene-to-Naphthalene Rearrangement
Das S and Wu J
Organic Letters, 17(23), 5854-5857 (2015)
A Novel Synthesis of Carboxylic Esters from 2-Methyl-4, 6-pyrimidyl Dicarbonates and Grignard Reagents
Lee J
Bulletin of the Korean Chemical Society,, 32(5), 1765-1768 (2011)
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