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Merck
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文件

558028

Sigma-Aldrich

(S)-(+)-4-戊烯-2-醇

95%

同義詞:

(2S)-4-Penten-2-ol, (2S)-Pent-4-en-2-ol, (S)-(+)-Pent-4-en-2-ol, (S)-(-)-Pent-4-en-2-ol, (S)-4-Penten-2-ol

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About This Item

線性公式:
H2C=CHCH2CH(OH)CH3
CAS號碼:
55563-79-6
分子量：:
86.13
MDL號碼:
MFCD03427200
分類程式碼代碼:
12352002
PubChem物質ID:
24879714
NACRES:
NA.22

化驗

95%

光學活性

[α]20/D +5.0°, c = 1% in chloroform

折射率

n20/D 1.4240 (lit.)

bp

115-116 °C (lit.)

密度

0.837 g/mL at 25 °C (lit.)

SMILES 字串

C[C@H](O)CC=C

InChI

1S/C5H10O/c1-3-4-5(2)6/h3,5-6H,1,4H2,2H3/t5-/m0/s1

InChI 密鑰

ZHZCYWWNFQUZOR-YFKPBYRVSA-N

相關類別

應用

(S)-(+)-4-Penten-2-ol can be used:
  • As an intermediate in one of the key synthetic steps for the preparation of undecenolide (−)-cladospolide C.
  • To prepare a carboxamide derivative as a key intermediate for the preparation of (−)-iso-cladospolide B1.
  • To prepare S-enantiomers of hydroxyeicosa tetraenoic acid named 19-HETE.
  • To prepare an acryloyl ester derivative by reacting with acryloyl chloride, which is a key intermediate for the synthesis of parasorbic acid.

象形圖

Flame
GHS02

訊號詞

Warning

危險聲明

H226

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

78.0 °F - closed cup

閃點（°C）

25.56 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析證明 (COA)

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A practical, stereospecific route to 18-, 19-, and 20-hydroxyeicosa-5 (Z), 8 (Z), 11 (Z), 14 (Z)-tetraenoic acids (18-, 19-, and 20-HETEs)
Gopal VR, et al.
Tetrahedron Letters, 45(12), 2563-2565 (2004)
Enantioselective total synthesis of iso-cladospolide B, cladospolide C and cladospolide B from tartaric acid
Prasad KR and Gandi VR
Tetrahedron Asymmetry, 22(5), 499-505 (2011)
A Chemoenzymatic Total Synthesis of the Undecenolide (−)-Cladospolide C
Banwell MG, et al.
Australian Journal of Chemistry, 58(7), 511-516 (2005)
Asymmetric synthesis of goniothalamin, hexadecanolide, massoia lactone, and parasorbic acid via sequential allylboration-esterification ring-closing metathesis reactions
Ramachandran PV, et al.
Tetrahedron Letters, 41(5), 583-586 (2000)

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