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Merck
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文件

529680

Sigma-Aldrich

氯化亚锰 水合物

99.999% trace metals basis

同義詞:

Manganese chloride hydrate

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About This Item

線性公式:
MnCl2 · xH2O
CAS號碼:
分子量::
125.84 (anhydrous basis)
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

99.999% trace metals basis

反應適用性

core: manganese
reagent type: catalyst

mp

122 °C (lit.)

密度

1.913 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

O.Cl[Mn]Cl

InChI

1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2

InChI 密鑰

BXRRQHBNBXJZBQ-UHFFFAOYSA-L

應用

Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - STOT RE 2

標靶器官

Brain

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析證明 (COA)

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存取文件庫

Cahiez, G.; Laboue, B.
Tetrahedron Letters, 33, 4439-4439 (1992)
Fujii, H.; Oshima, K.; Utimoto, K.
Tetrahedron Letters, 32, 6147-6147 (1991)

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