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525693

Sigma-Aldrich

6-溴-2-吡啶甲醛

97%

同義詞:

2-溴-6-甲酰基吡啶, 2-溴吡啶-6-甲醛, 2-溴吡啶基-6-甲醛, 2-甲酰基-6-溴吡啶, 6-溴-2-吡啶甲醛, 6-溴-2-甲酰基吡啶, 6-溴吡啶-2-醛

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About This Item

經驗公式(希爾表示法):
C6H4BrNO
CAS號碼:
分子量::
186.01
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

一般說明

6-溴-2-吡啶甲醛是一种吡啶衍生物。它参与了中位取代的反式 -A2B2-卟啉的合成。

應用

6-溴-2-吡啶甲醛可用于合成以下物质:
  • 6-([2,2'-二(1,3-二硫环内酯)]-4-基)吡啶醛
  • 三条臂之中的某一条上有 3-甲酰基-苯基取代基的 Tpy 核的三(2-吡啶基甲基)胺(Tpy)衍生物
  • 顺式反式 4-(6-溴吡啶-2-基)-3-甲基-3-苯基氧杂环丁烷-2-酮
  • 6-(2,4,6-三异丙基苯基)-2-吡啶甲醛
三[(吡啶基)甲基]胺配体的有用合成砌块。
用于研究铑催化的还原性羟醛与二乙烯基酮偶合生成 β-羟基烯酮的底物。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Steric and Electronic Effects in the Formation and Carbon Disulfide Reactivity of Dinuclear Nickel Complexes Supported by Bis (iminopyridine) Ligands.
Bheemaraju A, et al.
Organometallics, 32(10), 2952-2962 (2013)
Awatef Ayadi et al.
Beilstein journal of organic chemistry, 11, 1379-1391 (2015-10-02)
The synthesis and full characterization of two tetrathiafulvalene-appended azine ligands, namely 2-([2,2'-bi(1,3-dithiolylidene)]-4-yl)-6-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L1) and 5-([2,2'-bi(1,3-dithiolylidene)]-4-yl)-2-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L2) are described. The crystal structure of ligand L1 indicates that the ligand is completely planar with the presence of a strong intramolecular N3-H3···O1 hydrogen
NHC-Promoted asymmetric β-lactone formation from arylalkylketenes and electron-deficient benzaldehydes or pyridinecarboxaldehydes.
Douglas J, et al.
The Journal of Organic Chemistry, 78(8), 3925-3938 (2013)
Magdalena M Makowska-Grzyska et al.
Inorganic chemistry, 42(23), 7472-7488 (2003-11-11)
Divalent manganese, cobalt, nickel, and zinc complexes of 6-Ph(2)TPA (N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine; [(6-Ph(2)TPA)Mn(CH(3)OH)(3)](ClO(4))(2) (1), [(6-Ph(2)TPA)Co(CH(3)CN)](ClO(4))(2) (2), [(6-Ph(2)TPA)Ni(CH(3)CN)(CH(3)OH)](ClO(4))(2) (3), [(6-Ph(2)TPA)Zn(CH(3)CN)](ClO(4))(2) (4)) and 6-(Me(2)Ph)(2)TPA (N,N-bis((6-(3,5-dimethyl)phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine; [(6-(Me(2)Ph)(2)TPA)Ni(CH(3)CN)(2)](ClO(4))(2) (5) and [(6-(Me(2)Ph)(2)TPA)Zn(CH(3)CN)](ClO(4))(2) (6)) have been prepared and characterized. X-ray crystallographic characterization of 1A.CH(3)()OH and 1B.2CH(3)()OH (differing solvates
Francesca A Scaramuzzo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(49), 16809-16813 (2013-11-01)
Reliable determination of the enantiomeric excess of free amino acids can be obtained by measuring the induced circular dichroism of a multicomponent assembly formed by a modified tris(2-pyridylmethyl)amine ligand, a zinc salt, and the amino acid of interest. The systems

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