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518018

Sigma-Aldrich

碘化锂

greener alternative

99.9% trace metals basis

同義詞:

Lithium(1+)iodide

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About This Item

線性公式:
LiI
CAS號碼:
分子量::
133.85
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23
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品質等級

化驗

99.9% trace metals basis

形狀

powder

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

雜質

≤1500.0 ppm Trace Metal Analysis

mp

446 °C (lit.)

密度

3.49 g/mL at 25 °C (lit.)

環保替代類別

SMILES 字串

[Li+].[I-]

InChI

1S/HI.Li/h1H;/q;+1/p-1

InChI 密鑰

HSZCZNFXUDYRKD-UHFFFAOYSA-M

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一般說明

我们竭诚为您带来符合一项或多项绿色化学12项原则要求的绿色替代产品。该产品为增强型,提高了能源效率。点击此处以获取更多信息。
碘化锂被广泛用作染料敏化太阳能电池和Li-S电池的电解质添加剂,因为它可以延长循环寿命。它可作为磷光体用于中子检测。

應用

碘化锂(LiI)可用于电解质添加剂:

  • 制备可生物降解的聚合物电解质。大米淀粉与LiI复合物提高离子电导率,是因为LiI的添加增加了移动电荷载体的数量。
  • 对于Li-S电池,LiI在阳极和阴极表面都形成了保护膜,并组织多硫化物在阴极侧溶解,这显著提高了电池倍率性能。
它还可用于制备Li-基闪烁体,该闪烁体具有增强的热中子检测效率。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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存取文件庫

Feixiang Wu et al.
Advanced materials (Deerfield Beach, Fla.), 27(1), 101-108 (2014-11-05)
Lithium Iodide (LiI) is reported as a promising electrolyte additive for lithium-sulfur batteries. It induces formation of Li-ion-permeable protective coatings on both positive and negative electrodes, which prevent the dissolution of polysulfides on the cathode and reduction of polysulfides on
Seon-Joo Choi et al.
ACS applied materials & interfaces, 10(37), 31404-31412 (2018-08-28)
All-solid-state lithium batteries (ASSLBs) based on sulfide solid electrolytes (SEs) have received great attention because of the high ionic conductivity of the SEs, intrinsic thermal safety, and higher energy density achievable with a Li metal anode. However, studies on practical
Yu-il Kang et al.
ChemSusChem, 8(22), 3799-3804 (2015-10-17)
Dye-sensitized solar cells (DSCs) with long-term stability are produced using polymer-gel electrolytes (PGEs). In this study, we introduce the formation of PGEs using in situ gelation with poly(methyl methacrylate) (PMMA) particles and graphene fillers that are pre-deposited on the counter electrodes.
Jianjian Lin et al.
Scientific reports, 4, 5769-5769 (2014-08-30)
Three-dimensional (3D) hierarchical nanoscale architectures comprised of building blocks, with specifically engineered morphologies, are expected to play important roles in the fabrication of 'next generation' microelectronic and optoelectronic devices due to their high surface-to-volume ratio as well as opto-electronic properties.
Jung-Che Tsai et al.
Chemistry, an Asian journal, 10(9), 1932-1939 (2015-07-15)
Mesoporous cobalt sulfide nanotube arrays on FTO-coated glass were synthesized by combining three simple technologies: the selective etching of ZnO sacrificial templates, mesoporous Co3 O4 formation from cobalt-chelated chitosan, and ion-exchange reaction (IER). The mesoporous Co3 O4 nanotubes composed of

文章

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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