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重要文件

465151

Sigma-Aldrich

对苯二甲酸双(2-羟乙基)酯

同義詞:

对苯二甲酸二乙酯二乙二醇酯, 对苯二甲酸双(β-羟乙基)酯, 对苯二甲酸双(2-羟乙基)酯, 对苯二甲酸双(乙二醇)酯, 对苯二甲酸双(羟乙基)酯

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About This Item

線性公式:
C6H4-1,4-(CO2CH2CH2OH)2
CAS號碼:
分子量::
254.24
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23
暫時無法取得訂價和供貨情況

形狀

solid

mp

106-109 °C (lit.)

SMILES 字串

OCCOC(=O)c1ccc(cc1)C(=O)OCCO

InChI

1S/C12H14O6/c13-5-7-17-11(15)9-1-2-10(4-3-9)12(16)18-8-6-14/h1-4,13-14H,5-8H2

InChI 密鑰

QPKOBORKPHRBPS-UHFFFAOYSA-N

一般說明

双(2-羟乙基)对苯二甲酸酯属于称为二醇或乙二醇类的单体。它被广泛用于合成不饱和聚酯树脂、聚对苯二甲酸乙二醇酯(PET)和新的生物相容性聚合物体系。BHET 还可以用作聚酯树脂和刚性或柔性聚氨酯的增塑剂。此外,由于其优异的生物相容性和机械性能,BHET及其衍生物也被研究用于生物医学应用,包括药物输送和组织工程。[1]

應用

双(2-羟乙基)对苯二甲酸酯可作为单体,以制备可生物降解的芳香-脂肪族共聚酯,用于可持续软包装应用。引入BHET合成砌块可提供一个有前景的方法,为提高生物降解塑料的性能和促进可持续包装的解决方案。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析證明 (COA)

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Study on depolymerization of waste polyethylene terephthalate into monomer of bis(2-hydroxyethyl terephthalate
Guoxi Xi, et al.
Polymer Degradation and Stability, 87, 117-120 (2005)
Yanbo Zhang et al.
International journal of biological macromolecules, 166, 251-258 (2020-10-31)
Hydrothermal degradation was used to pretreat terylene with an aim of noticeably improving the yield of fermentable monomers: terephthalic acid (TPA), mono (2- hydroxyethyl) terephthalic acid (MHET), bis-hydroxyethyl terephthalate (BHET), and ethylene glycol (EG). After 0.5 h of reaction time at
Martin Eckardt et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 36(12), 1882-1894 (2019-09-04)
Linear and cyclic oligomers are unavoidable non-intentionally added substances (NIAS) present in food contact materials made from common polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT) and polyester coatings. Although polyester oligomers can migrate into fats in significant amounts
Uschara Thumarat et al.
Journal of bioscience and bioengineering, 120(5), 491-497 (2015-04-26)
This study described the genetic map of tandem genes (est1 and est119) encoding cutinase-type polyesterases in Thermobifida alba AHK119 and comparison of wild type and mutant enzymes of Est1 and Est119. Two genes were independently and constitutively expressed. The activity
Makoto Furukawa et al.
ChemSusChem, 11(23), 4018-4025 (2018-10-07)
Enzymatic degradation of poly(ethylene terephthalate) (PET) is promising because this process is safer than conventional industrial approaches. Recently, a cationic PET hydrolase (PETase) was identified from Ideonella sakaiensis. Pre-incubation of a low-crystallinity PET film with anionic surfactants prior to initiating

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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