449563

硼烷二苯基膦复合物

98%

• 同義詞: (Diphenylphosphine)trihydroboron
• 線性公式: (C₆H₅)₂PH·BH₃
• CAS號碼: 41593-58-2
• 分子量：: 200.02
• MDL號碼: MFCD00274254
• 分類程式碼代碼: 12352002
• PubChem物質ID: 24868492
• NACRES: NA.22

屬性

• 化驗: 98%
• 形狀: solid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Reductions; reagent type: reductant
• bp: 148-150 °C/10 mmHg (lit.)
• mp: 47-50 °C (lit.)
• SMILES 字串: B.[H]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
• InChI 密鑰: XUFGOLYVDOBYLK-UHFFFAOYSA-N

描述

應用

Reactant for:

• Nucleophilic addition reactions (anion)
• Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
• Deprotonation reactions
• Catalytic coupling with alkynyl bromides
• Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
• Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
• Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

安全資訊

• 象形圖: GHS02
• 訊號詞: Danger
• 危險聲明: H261
• 防範說明: P231 + P232 - P422
• 危險分類: Water-react 2
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges