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Merck
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442666

Sigma-Aldrich

(+)-(18-冠-6)-2,3,11,12-四羧酸

97%

同義詞:

(2R,3R,11R,12R)-1,4,7,10,13,16-六氧环十八烷-2,3,11,12-四羧酸

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About This Item

經驗公式（希爾表示法）:
C16H24O14
CAS號碼:
61696-54-6
分子量：:
440.35
Beilstein:
4240375
MDL號碼:
MFCD00040514
分類程式碼代碼:
12352005
PubChem物質ID:
24867945
NACRES:
NA.22

化驗

97%

光學活性

[α]20/D +62°, c = 1 in methanol

mp

210-212 °C (lit.)

官能基

carboxylic acid
ether

SMILES 字串

OC(=O)[C@@H]1OCCOCCO[C@H]([C@@H](OCCOCCO[C@H]1C(O)=O)C(O)=O)C(O)=O

InChI

1S/C16H24O14/c17-13(18)9-10(14(19)20)29-7-3-26-4-8-30-12(16(23)24)11(15(21)22)28-6-2-25-1-5-27-9/h9-12H,1-8H2,(H,17,18)(H,19,20)(H,21,22)(H,23,24)/t9-,10-,11-,12-/m1/s1

InChI 密鑰

FZERLKNAJSFDSQ-DDHJBXDOSA-N

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應用

该冠醚的四羧酸氯化物与邻位和对位亚二甲苯基二胺反应生成高产量的手性封端配体。在毛细管区带电泳中用作手性选择剂，分离不同光学活性的胺。合成单酰胺类化合物。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析證明 (COA)

Lot/Batch Number
07624JQ
07408DR
06812EN
05905BA
05623BS

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Je Young Park et al.
Chirality, 24(5), 427-431 (2012-04-18)
3-Amino-5-phenyl (or 5-methyl)-1,4-benzodiazepin-2-ones, which are chiral precursors of anti-respiratory syncytial virus active agents, were resolved on three different chiral stationary phases (CSPs) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid or (3,3'-diphenyl-1,1'-binaphthyl)-20-crown-6. Among the three CSPs, the CSP that is based on (3,3'-diphenyl-1,1'-binaphthyl)-20-crown-6 and
Su Jin Lee et al.
Journal of chromatography. A, 1188(2), 318-321 (2008-03-19)
Racemic vigabatrin, an anticonvulsant drug used for the treatment of epilepsy, and its analogue gamma-amino acids were resolved without derivatization on liquid chromatographic chiral stationary phases (CSPs) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid. Between the two CSPs which contain 3 methylene-unit or
Taeho Lee et al.
Journal of chromatography. A, 1217(8), 1425-1428 (2010-01-12)
(-)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid-bonded silica was used as the chiral stationary phase in capillary electrochromatography (CEC) for enantioseparation of some alpha-amino acids. Separation data in CEC were measured in mobile phases of varying pH, and composition of methanol and buffer, and compared
Suzanne Anouti et al.
Electrophoresis, 30(1), 2-10 (2008-12-25)
A new methodology based on heart-cutting 2-D CE in a single capillary was developed for the chiral separation of a mixture of 22 underivatized amino acids. The first dimension is performed in an achiral BGE (2.3 M acetic acid, pH
Suzanne Anouti et al.
Electrophoresis, 31(6), 1029-1035 (2010-03-24)
The use of transient moving chemical reaction boundary (tMCRB) was investigated for the on-line preconcentration of native amino acids in heart-cutting 2D-CE with multiple detection points using contactless conductivity detection. The tMCRB focusing was obtained by using ammonium formate (pH
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