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重要文件

436372

Sigma-Aldrich

4,4′-二氨基二苯硫醚

98%

同義詞:

4,4′-硫化二苯胺

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About This Item

線性公式:
S(C6H4NH2)2
CAS號碼:
分子量::
216.30
Beilstein:
1875513
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

98%

形狀

solid

mp

105-107 °C (lit.)

官能基

thioether

SMILES 字串

Nc1ccc(Sc2ccc(N)cc2)cc1

InChI

1S/C12H12N2S/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

InChI 密鑰

ICNFHJVPAJKPHW-UHFFFAOYSA-N

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一般說明

4,4′-Diaminodiphenyl sulfide is a diaminodiphenyl analog. On oral administration to rats, it induces haematological and pathological changes indicative of erythrocyte destruction.[1] It has been reported to generate hydrogen peroxide in erythrocytes in vitro.[2] Enzymatic oxidation of 4,4′-diaminodiphenyl sulfide to their sulfoxide derivatives in guinea pig liver homogenates has been reported.[3]

應用

4,4′-Diaminodiphenyl sulfide may be employed for the fabrication of quantum wires and quantum dots by chemical vapor deposition.[4]
It may be used for the preparation of the following:
  • polypyromellitimides[5]
  • sulfur-containing copolyimides[6]
  • polyamides[7]

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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The enzymatic formation of sulfoxides: the oxidation of chlorpromazine and 4,4'-diaminodiphenyl sulfide by guinea pig liver microsomes.
J R GILLETTE et al.
The Journal of pharmacology and experimental therapeutics, 130, 262-267 (1960-11-01)
R Munday et al.
Journal of applied toxicology : JAT, 5(6), 414-417 (1985-12-01)
Diphenyl disulphide, 4,4'-diaminodiphenyl disulphide, 2,2'-diaminodiphenyl disulphide, 4,4'-dimethyldiphenyl disulphide and 4,4'-dinitrodiphenyl disulphide, when administered orally to rats, induced haematological and pathological changes indicative of erythrocyte destruction in vivo. No evidence of haemolysis was detected, however, in animals receiving diphenyl disulphide-2,2'-dicarboxylic acid
Quantum wire and dot formation by chemical vapor deposition and molecular layer deposition of one-dimensional conjugated polymer.
Yoshimura T, et al.
Applied Physics Letters, 60(3), 268-270 (1992)
R Munday
Journal of applied toxicology : JAT, 5(6), 409-413 (1985-12-01)
Diphenyl disulphide has been shown to generate hydrogen peroxide in erythrocytes in vitro. It also induces oxidative damage (reversible and irreversible haemoglobin oxidation, depletion of non-protein and protein-bound thiols) in these cells. Such changes were also recorded in erythrocytes exposed
Polycondensation of pyridine-2,6-dicarboxylic acid with some di-and tetraamino compounds.
Banihashemi A and Eghbali M.
Journal of Polymer Science, 14(11), 2659-2664 (1976)

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