425206

2-(甲硫基)环己酮

98%

• 線性公式: CH₃SC₆H₉(=O)
• CAS號碼: 52190-35-9
• 分子量：: 144.23
• MDL號碼: MFCD00209603
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24866619

屬性

• 化驗: 98%
• 形狀: liquid
• 折射率: n20/D 1.508 (lit.)
• bp: 45 °C/10.1 mmHg (lit.)
• 密度: 1.069 g/mL at 25 °C (lit.)
• SMILES 字串: CSC1CCCCC1=O
• InChI: 1S/C7H12OS/c1-9-7-5-3-2-4-6(7)8/h7H,2-5H2,1H3
• InChI 密鑰: QFABNUVNDKOIEH-UHFFFAOYSA-N

描述

一般說明

2-(Methylthio)cyclohexanone is a 2-substituted cyclohexanone. The proportion of axial and equatorial conformation has been measured in chloroform by the Eliel method. It suggests that the in chloroform steric effect dominates over polar effect in contributing to the conformational preference. The stereoselectivity of the reduction of 2-(methylthio)cyclohexanone using different hydrides has been studied.

應用

2-(Methylthio)cyclohexanone may be used as a ketone substrate for the synthesis of cyclic nitrones, by reacting with aspergillusol A.

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 192.2 °F - closed cup
• 閃點（°C）: 89 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter